Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines

Tosapol Maluangnont, Kazuma Gotoh, Kazuya Fujiwara, Michael M. Lerner

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

A rich chemistry of ternary graphite intercalation compounds (GICs) containing alkali metal cations and amines or polyamines has been developed recently in our labs. Monolayer and bilayer structures for a range of amines and polyamines, including hexylamine, 1,2-diaminopropane, and diethylenetriamine, have been prepared chemically as stage 1 or 2 GICs. While these and related intercalates have been studied in detail with other layered host structures, there have been few reported analogs in graphite chemistry. However, our recent results indicate that under appropriate synthetic conditions the intercalation of amines into graphite may be comparable to that of other layered hosts, and may lead to an alternate chemical route to graphenes. The synthetic strategies employed and the structural and compositional details of the graphite intercalation compounds recently obtained (from XRD, NMR and thermal analysis) will be described.

Original languageEnglish
Title of host publicationIOP Conference Series: Materials Science and Engineering
PublisherInstitute of Physics Publishing
Volume18
EditionSYMPOSIUM 3
DOIs
Publication statusPublished - 2011
Event3rd International Congress on Ceramics, ICC 2011 - Osaka, Japan
Duration: Nov 14 2010Nov 18 2010

Other

Other3rd International Congress on Ceramics, ICC 2011
CountryJapan
CityOsaka
Period11/14/1011/18/10

Fingerprint

Alkali Metals
Intercalation compounds
Polyamines
Alkali metals
Amines
Cations
Graphite
Positive ions
Intercalation
Thermoanalysis
Monolayers
Nuclear magnetic resonance

ASJC Scopus subject areas

  • Materials Science(all)
  • Engineering(all)

Cite this

Maluangnont, T., Gotoh, K., Fujiwara, K., & Lerner, M. M. (2011). Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines. In IOP Conference Series: Materials Science and Engineering (SYMPOSIUM 3 ed., Vol. 18). [062004] Institute of Physics Publishing. https://doi.org/10.1088/1757-899X/18/6/062004

Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines. / Maluangnont, Tosapol; Gotoh, Kazuma; Fujiwara, Kazuya; Lerner, Michael M.

IOP Conference Series: Materials Science and Engineering. Vol. 18 SYMPOSIUM 3. ed. Institute of Physics Publishing, 2011. 062004.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Maluangnont, T, Gotoh, K, Fujiwara, K & Lerner, MM 2011, Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines. in IOP Conference Series: Materials Science and Engineering. SYMPOSIUM 3 edn, vol. 18, 062004, Institute of Physics Publishing, 3rd International Congress on Ceramics, ICC 2011, Osaka, Japan, 11/14/10. https://doi.org/10.1088/1757-899X/18/6/062004
Maluangnont T, Gotoh K, Fujiwara K, Lerner MM. Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines. In IOP Conference Series: Materials Science and Engineering. SYMPOSIUM 3 ed. Vol. 18. Institute of Physics Publishing. 2011. 062004 https://doi.org/10.1088/1757-899X/18/6/062004
Maluangnont, Tosapol ; Gotoh, Kazuma ; Fujiwara, Kazuya ; Lerner, Michael M. / Donor-type graphite intercalation compounds containing alkali metal cations with amines and polyamines. IOP Conference Series: Materials Science and Engineering. Vol. 18 SYMPOSIUM 3. ed. Institute of Physics Publishing, 2011.
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