Distannane mediated reaction of N-acyliminium ion pools with alkyl halides. A chain mechanism involving radical addition followed by electron transfer

Tomokazu Maruyama, Seiji Suga, Jun ichi Yoshida

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29 Citations (Scopus)

Abstract

Hexabutyldistannane was found to be an effective mediator allowing the reaction of N-acyliminium ion pools with alkyl halides. A chain mechanism involving the addition of an alkyl radical generated from an alkyl halide to an N-acyliminium ion followed by the one-electron reduction of the resulting radical-cation by distannane was proposed.

Original languageEnglish
Pages (from-to)6519-6525
Number of pages7
JournalTetrahedron
Volume62
Issue number27
DOIs
Publication statusPublished - Jul 3 2006
Externally publishedYes

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ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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