Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates

Akira Sakakura, Shoko Nakagawa, Kazuaki Ishihara

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

A protocol for ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by bulky diarylammonium pentafluorobenzenesulfonate is described. We also present procedures for the synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammonium pentafluorobenzenesulfonate. The present ester condensation proceeds well under mild conditions even without the removal of generated water. The synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammonium pentafluorobenzenesulfonate will take b5 days. The ester condensation reactions will take -6 h to 3 days.

Original languageEnglish
Pages (from-to)1746-1751
Number of pages6
JournalNature protocols
Volume2
Issue number7
DOIs
Publication statusPublished - Jun 28 2007
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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