Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates.

Akira Sakakura, Shoko Nakagawa, Kazuaki Ishihara

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A protocol for ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by bulky diarylammonium pentafluorobenzenesulfonate is described. We also present procedures for the synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammonium pentafluorobenzenesulfonate. The present ester condensation proceeds well under mild conditions even without the removal of generated water. The synthesis of N-(2,6-diisopropylphenyl)-N-mesitylammonium pentafluorobenzenesulfonate will take approximately 5 days. The ester condensation reactions will take approximately 6 h to 3 days.

Original languageEnglish
Pages (from-to)1746-1751
Number of pages6
JournalNature Protocols
Volume2
Issue number7
DOIs
Publication statusPublished - 2007
Externally publishedYes

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Condensation
Esters
Condensation reactions
Carboxylic Acids
Alcohols
Water

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates. / Sakakura, Akira; Nakagawa, Shoko; Ishihara, Kazuaki.

In: Nature Protocols, Vol. 2, No. 7, 2007, p. 1746-1751.

Research output: Contribution to journalArticle

Sakakura, Akira ; Nakagawa, Shoko ; Ishihara, Kazuaki. / Direct ester condensation catalyzed by bulky diarylammonium pentafluorobenzenesulfonates. In: Nature Protocols. 2007 ; Vol. 2, No. 7. pp. 1746-1751.
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