Direct determination of low-dimensional structures: Synchrotron X-ray scattering on one-dimensional charge-ordered MMX-chain complexes

Yusuke Wakabayashi, Atsushi Kobayashi, Hiroshi Sawa, Hiroyuki Ohsumi, Naoshi Ikeda, Hiroshi Kitagawa

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A powerful method to determine the hidden structural parameters in functional molecules has been developed. Local valence arrangements that dominate the material properties are sometimes not three-dimensionally ordered. This method that comprises diffuse X-ray scattering and resonant X-ray scattering is suitable in such cases. Using this method, we present clear evidence of the low-dimensional valence arrangement in two halogen-bridged one-dimensional metal complexes, so-called MMX chains. This family allows us to control many physical and structural parameters by chemical substitution of bridging halogen, counterions, or metal ions, and one of our samples carries an unusual metallic phase. It is demonstrated with this complex that the present method makes it possible to have microscopic insight to low-dimensionally ordered systems.

Original languageEnglish
Pages (from-to)6676-6682
Number of pages7
JournalJournal of the American Chemical Society
Volume128
Issue number20
DOIs
Publication statusPublished - May 24 2006

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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