Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

Kouichi Matsumoto; Koji Ueoka; Shinkiti Suzuki; Seiji Suga; Jun ichi Yoshida

doi:10.1016/j.tet.2009.09.020

Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

Kouichi Matsumoto, Koji Ueoka, Shinkiti Suzuki, Seiji Suga, Jun ichi Yoshida

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.

Original language	English
Pages (from-to)	10901-10907
Number of pages	7
Journal	Tetrahedron
Volume	65
Issue number	52
DOIs	https://doi.org/10.1016/j.tet.2009.09.020
Publication status	Published - Dec 26 2009
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/j.tet.2009.09.020

Fingerprint Dive into the research topics of 'Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals'. Together they form a unique fingerprint.

Cite this

@article{dfd47aa203db44b89c1a4806d27d57a2,

title = "Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals",

abstract = "Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.",

author = "Kouichi Matsumoto and Koji Ueoka and Shinkiti Suzuki and Seiji Suga and Yoshida, {Jun ichi}",

year = "2009",

month = dec,

day = "26",

doi = "10.1016/j.tet.2009.09.020",

language = "English",

volume = "65",

pages = "10901--10907",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Limited",

number = "52",

}

TY - JOUR

T1 - Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

AU - Matsumoto, Kouichi

AU - Ueoka, Koji

AU - Suzuki, Shinkiti

AU - Suga, Seiji

AU - Yoshida, Jun ichi

PY - 2009/12/26

Y1 - 2009/12/26

N2 - Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.

AB - Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.

UR - http://www.scopus.com/inward/record.url?scp=70449730098&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70449730098&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2009.09.020

DO - 10.1016/j.tet.2009.09.020

M3 - Article

AN - SCOPUS:70449730098

VL - 65

SP - 10901

EP - 10907

JO - Tetrahedron

JF - Tetrahedron

SN - 0040-4020

IS - 52

ER -