Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

Kouichi Matsumoto; Koji Ueoka; Shinkiti Suzuki; Seiji Suga; Jun ichi Yoshida

doi:10.1016/j.tet.2009.09.020

Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

Kouichi Matsumoto, Koji Ueoka, Shinkiti Suzuki, Seiji Suga, Jun ichi Yoshida

Research output: Contribution to journal › Article

29 Citations (Scopus)

Abstract

Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.

Original language	English
Pages (from-to)	10901-10907
Number of pages	7
Journal	Tetrahedron
Volume	65
Issue number	52
DOIs	https://doi.org/10.1016/j.tet.2009.09.020
Publication status	Published - Dec 26 2009
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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Matsumoto, K., Ueoka, K., Suzuki, S., Suga, S., & Yoshida, J. I. (2009). Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals. Tetrahedron, 65(52), 10901-10907. https://doi.org/10.1016/j.tet.2009.09.020

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AU - Yoshida, Jun ichi

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