Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals

Kouichi Matsumoto, Koji Ueoka, Shinkiti Suzuki, Seiji Suga, Jun ichi Yoshida

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl ethers to give C-C bond formation products in good yields.

Original languageEnglish
Pages (from-to)10901-10907
Number of pages7
JournalTetrahedron
Volume65
Issue number52
DOIs
Publication statusPublished - Dec 26 2009
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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