Dipotassium di-μ-hydroxo-bis[(nitrilotriacetato-κ4N,O, O′,O″)chromium(III)] hexahydrate

Jong Ha Choi; Takayoshi Suzuki; Sumio Kaizaki

doi:10.1107/S160053680301883X

Dipotassium di-μ-hydroxo-bis[(nitrilotriacetato-κ⁴N,O, O′,O″)chromium(III)] hexahydrate

Jong Ha Choi, Takayoshi Suzuki, Sumio Kaizaki

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The crystal structure of the title compound, K₂[Cr ₂(C₆H₆NO₆)₂(OH) ₂]·6H₂O or K₂[Cr₂(μ-OH) ₂(nta)₂]-6H₂O (nta = nitrilotriacetate), is composed of a dinuclear hydroxo-bridged chromium(III) complex anion, potassium cation and water molecules. Each Cr^III ion is in a distorted octahedral environment and coordinated by one nitrogen and three carboxylate O atoms of the nta^3- ligand plus two bridging hydroxo O atoms. The dinuclear complex anion possesses 2/m crystallographic symmetry. The Cr-O(μ-OH) bond lengths are 1.937 (4) and 1.951 (4) Å. The Cr-N and Cr-O bond distances of the nta^3- ligand are 2.054 (4) and 1.968(3)-1.983 (3) Å, while the HO-Cr-OH and Cr-OH-Cr angles are 80.46 (16) and 99.54 (16)°, respectively.

Original language	English
Pages (from-to)	m812-m813
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	9
DOIs	https://doi.org/10.1107/S160053680301883X
Publication status	Published - Sep 1 2003
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Dipotassium di-μ-hydroxo-bis[(nitrilotriacetato-κ4N,O, O′,O″)chromium(III)] hexahydrate",

abstract = "The crystal structure of the title compound, K2[Cr 2(C6H6NO6)2(OH) 2]·6H2O or K2[Cr2(μ-OH) 2(nta)2]-6H2O (nta = nitrilotriacetate), is composed of a dinuclear hydroxo-bridged chromium(III) complex anion, potassium cation and water molecules. Each CrIII ion is in a distorted octahedral environment and coordinated by one nitrogen and three carboxylate O atoms of the nta3- ligand plus two bridging hydroxo O atoms. The dinuclear complex anion possesses 2/m crystallographic symmetry. The Cr-O(μ-OH) bond lengths are 1.937 (4) and 1.951 (4) {\AA}. The Cr-N and Cr-O bond distances of the nta3- ligand are 2.054 (4) and 1.968(3)-1.983 (3) {\AA}, while the HO-Cr-OH and Cr-OH-Cr angles are 80.46 (16) and 99.54 (16)°, respectively.",

author = "Choi, {Jong Ha} and Takayoshi Suzuki and Sumio Kaizaki",

year = "2003",

month = sep,

day = "1",

doi = "10.1107/S160053680301883X",

language = "English",

volume = "59",

pages = "m812--m813",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Dipotassium di-μ-hydroxo-bis[(nitrilotriacetato-κ4N,O, O′,O″)chromium(III)] hexahydrate

AU - Choi, Jong Ha

AU - Suzuki, Takayoshi

AU - Kaizaki, Sumio

PY - 2003/9/1

Y1 - 2003/9/1

N2 - The crystal structure of the title compound, K2[Cr 2(C6H6NO6)2(OH) 2]·6H2O or K2[Cr2(μ-OH) 2(nta)2]-6H2O (nta = nitrilotriacetate), is composed of a dinuclear hydroxo-bridged chromium(III) complex anion, potassium cation and water molecules. Each CrIII ion is in a distorted octahedral environment and coordinated by one nitrogen and three carboxylate O atoms of the nta3- ligand plus two bridging hydroxo O atoms. The dinuclear complex anion possesses 2/m crystallographic symmetry. The Cr-O(μ-OH) bond lengths are 1.937 (4) and 1.951 (4) Å. The Cr-N and Cr-O bond distances of the nta3- ligand are 2.054 (4) and 1.968(3)-1.983 (3) Å, while the HO-Cr-OH and Cr-OH-Cr angles are 80.46 (16) and 99.54 (16)°, respectively.

AB - The crystal structure of the title compound, K2[Cr 2(C6H6NO6)2(OH) 2]·6H2O or K2[Cr2(μ-OH) 2(nta)2]-6H2O (nta = nitrilotriacetate), is composed of a dinuclear hydroxo-bridged chromium(III) complex anion, potassium cation and water molecules. Each CrIII ion is in a distorted octahedral environment and coordinated by one nitrogen and three carboxylate O atoms of the nta3- ligand plus two bridging hydroxo O atoms. The dinuclear complex anion possesses 2/m crystallographic symmetry. The Cr-O(μ-OH) bond lengths are 1.937 (4) and 1.951 (4) Å. The Cr-N and Cr-O bond distances of the nta3- ligand are 2.054 (4) and 1.968(3)-1.983 (3) Å, while the HO-Cr-OH and Cr-OH-Cr angles are 80.46 (16) and 99.54 (16)°, respectively.

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DO - 10.1107/S160053680301883X

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VL - 59

SP - m812-m813

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 9

ER -

Dipotassium di-μ-hydroxo-bis[(nitrilotriacetato-κ⁴N,O, O′,O″)chromium(III)] hexahydrate

Abstract

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