TY - JOUR
T1 - Dilute Hydrofluoric Acid as a Fluorinating Agent
T2 - Iodofluorination of Olefins with Dilute Hydrofluoric Acid, N -Iodosuccinimide, and a Phase Transfer Catalyst
AU - Kuroboshi, Manabu
AU - Hiyama, Tamejiro
PY - 1991/3/1
Y1 - 1991/3/1
N2 -
Regio-, stereo-, and chemoselective iodofluorination of olefins is readily effected under a two-phase system using dilute hydrofluoric acid, N-iodosuccinimide, and tetrabutylammonium fluoride as a phase transfer catalyst. Additional use of potassium hydrogen fluoride (KHF
2
) enhanced the yields of fluoro-iodo adducts and suppressed the formation of iodohydrins as byproducts.
AB -
Regio-, stereo-, and chemoselective iodofluorination of olefins is readily effected under a two-phase system using dilute hydrofluoric acid, N-iodosuccinimide, and tetrabutylammonium fluoride as a phase transfer catalyst. Additional use of potassium hydrogen fluoride (KHF
2
) enhanced the yields of fluoro-iodo adducts and suppressed the formation of iodohydrins as byproducts.
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U2 - 10.1055/s-1991-20672
DO - 10.1055/s-1991-20672
M3 - Article
AN - SCOPUS:85064389190
SN - 0936-5214
VL - 1991
SP - 185
EP - 186
JO - Synlett
JF - Synlett
IS - 3
ER -