Dibromido(η5-pentamethylcyclopentadienyl) (5-phenyldibenzophosphole-kP)iridium(III) dichloromethane solvate

Mai Kotera; Takayoshi Suzuki

doi:10.1107/S1600536807026621

Dibromido(η⁵-pentamethylcyclopentadienyl) (5-phenyldibenzophosphole-kP)iridium(III) dichloromethane solvate

Mai Kotera, Takayoshi Suzuki

Research output: Contribution to journal › Article › peer-review

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Abstract

The title compound, [IrBr2(⁵-C10H15)(C18H13P)]·CH2Cl2, is the first example of an iridium(III) phosphole complex to be characterized by X-ray crystallographic analysis. The Ir - P bond length is 2.2828 (15) Å, which is shorter by 0.04 Å than that of the analogous PPh3 complex. This is indicative of the steric compactness of 5-phenyl-dibenzophosphole compared with PPh3. The dibenzophosphole portion of the ligand is nearly planar, and the planes of the dibenzophosphole units of neighbouring mol-ecules are stacked on top of each other to form a dimer in the crystal structure. The closest C⋯C distances between the planes are 3.9 Å.

Original language	English
Pages (from-to)	m1818
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	7
DOIs	https://doi.org/10.1107/S1600536807026621
Publication status	Published - Jun 6 2007
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Dibromido(η5-pentamethylcyclopentadienyl) (5-phenyldibenzophosphole-kP)iridium(III) dichloromethane solvate",

abstract = "The title compound, [IrBr2(5-C10H15)(C18H13P)]·CH2Cl2, is the first example of an iridium(III) phosphole complex to be characterized by X-ray crystallographic analysis. The Ir - P bond length is 2.2828 (15) {\AA}, which is shorter by 0.04 {\AA} than that of the analogous PPh3 complex. This is indicative of the steric compactness of 5-phenyl-dibenzophosphole compared with PPh3. The dibenzophosphole portion of the ligand is nearly planar, and the planes of the dibenzophosphole units of neighbouring mol-ecules are stacked on top of each other to form a dimer in the crystal structure. The closest C⋯C distances between the planes are 3.9 {\AA}.",

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T1 - Dibromido(η5-pentamethylcyclopentadienyl) (5-phenyldibenzophosphole-kP)iridium(III) dichloromethane solvate

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Y1 - 2007/6/6

N2 - The title compound, [IrBr2(5-C10H15)(C18H13P)]·CH2Cl2, is the first example of an iridium(III) phosphole complex to be characterized by X-ray crystallographic analysis. The Ir - P bond length is 2.2828 (15) Å, which is shorter by 0.04 Å than that of the analogous PPh3 complex. This is indicative of the steric compactness of 5-phenyl-dibenzophosphole compared with PPh3. The dibenzophosphole portion of the ligand is nearly planar, and the planes of the dibenzophosphole units of neighbouring mol-ecules are stacked on top of each other to form a dimer in the crystal structure. The closest C⋯C distances between the planes are 3.9 Å.

AB - The title compound, [IrBr2(5-C10H15)(C18H13P)]·CH2Cl2, is the first example of an iridium(III) phosphole complex to be characterized by X-ray crystallographic analysis. The Ir - P bond length is 2.2828 (15) Å, which is shorter by 0.04 Å than that of the analogous PPh3 complex. This is indicative of the steric compactness of 5-phenyl-dibenzophosphole compared with PPh3. The dibenzophosphole portion of the ligand is nearly planar, and the planes of the dibenzophosphole units of neighbouring mol-ecules are stacked on top of each other to form a dimer in the crystal structure. The closest C⋯C distances between the planes are 3.9 Å.

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Dibromido(η⁵-pentamethylcyclopentadienyl) (5-phenyldibenzophosphole-kP)iridium(III) dichloromethane solvate

Abstract

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