Abstract
(2,4,6-Trifluorophenyl)- and (2,6-difluoropheny)boronic acids react with PdI(C6H4O-4-Me)(tmen) (tmen = N,N,N',N'- tetramethylethylenediamine) in the presence of Ag2O to produce cis-diarylpalladium complexes with a tmen ligand via intermolecular transfer of the fluorophenyl group from B to Pd. The isolated complexes undergo coupling of the two aryl ligands upon heating the solution to 45-60 °C to afford unsymmetrical biaryls.
| Original language | English |
|---|---|
| Pages (from-to) | 190-192 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 24 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 17 2005 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Cite this
Osakada, K., Onodera, H., & Nishihara, Y. (2005). Diarylpalladium complexes with a cis structure. Formation via transmetalation of arylboronic acids with an aryliodopalladium complex and intramolecular coupling of the aryl ligands, affording unsymmetrical biaryls. Organometallics, 24(2), 190-192. https://doi.org/10.1021/om049217i