Diamond anvil cell NMR

Research output: Contribution to journalArticle

Abstract

The history of challenges for diamond anvil cell NMR is reviewed in this article. Pros and cons of the newly emerging method are discussed first. All previous works are reviewed briefly. Our state-of-the-art techniques are presented in detail. These are (i) a new DAC design for large-volume sample to be compressed, (ii) a new RF probe design for higher sensitivity, and (iii) a magnetically tuned gasket for better static field. Using them, we have obtained high-resolution NMR spectra of liquid methanol to 4.5 GPa that is factor four larger than previous studies. These results and their implication are presented.

Original languageEnglish
Pages (from-to)324-332
Number of pages9
JournalReview of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
Volume15
Issue number4
DOIs
Publication statusPublished - 2005
Externally publishedYes

Fingerprint

Diamond
anvils
Diamonds
diamonds
Nuclear magnetic resonance
nuclear magnetic resonance
cells
Methanol
emerging
methyl alcohol
histories
probes
sensitivity
high resolution
Liquids
liquids

Keywords

  • DAC
  • High resolution NMR
  • Hydrogen bonding
  • Methanol
  • Relaxation
  • RF coil

ASJC Scopus subject areas

  • Chemistry (miscellaneous)

Cite this

Diamond anvil cell NMR. / Okuchi, Takuo.

In: Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu, Vol. 15, No. 4, 2005, p. 324-332.

Research output: Contribution to journalArticle

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