Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands

Hiromi Ohta; Kenji Harada; Koji Irie; Setsuo Kashino; Takashi Kambe; Genta Sakane; Takashi Shibahara; Satoshi Takamizawa; Wasuke Mori; Matsuo Nonoyama; Masakazu Hirotsu; Masaaki Kojima

doi:10.1246/cl.2001.842

Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands

Hiromi Ohta, Kenji Harada, Koji Irie, Setsuo Kashino, Takashi Kambe, Genta Sakane, Takashi Shibahara, Satoshi Takamizawa, Wasuke Mori, Matsuo Nonoyama, Masakazu Hirotsu, Masaaki Kojima

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

The reaction of Ni²⁺ with a tripodal hexadentate ligand (H₃L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) afforded the O-H⋯O bridged dinuclear [Ni₂(HL)₂] complex. When Ni²⁺ was allowed to react with H₃L in the presence of triethylamine (3 : 2 : 6), the linear trinuclear [Ni₃(L)₂] complex formed, where the central nickel(II) ion is bridged by six phenolate oxygen atoms to the terminal nickel(II) ions.

Original language	English
Pages (from-to)	842-843
Number of pages	2
Journal	Chemistry Letters
Issue number	8
DOIs	https://doi.org/10.1246/cl.2001.842
Publication status	Published - Jan 1 2001

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Chemistry(all)

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Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands. / Ohta, Hiromi; Harada, Kenji; Irie, Koji; Kashino, Setsuo; Kambe, Takashi; Sakane, Genta; Shibahara, Takashi; Takamizawa, Satoshi; Mori, Wasuke; Nonoyama, Matsuo; Hirotsu, Masakazu; Kojima, Masaaki.

In: Chemistry Letters, No. 8, 01.01.2001, p. 842-843.

Research output: Contribution to journal › Article › peer-review

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abstract = "The reaction of Ni2+ with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) afforded the O-H⋯O bridged dinuclear [Ni2(HL)2] complex. When Ni2+ was allowed to react with H3L in the presence of triethylamine (3 : 2 : 6), the linear trinuclear [Ni3(L)2] complex formed, where the central nickel(II) ion is bridged by six phenolate oxygen atoms to the terminal nickel(II) ions.",

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AU - Ohta, Hiromi

AU - Harada, Kenji

AU - Irie, Koji

AU - Kashino, Setsuo

AU - Kambe, Takashi

AU - Sakane, Genta

AU - Shibahara, Takashi

AU - Takamizawa, Satoshi

AU - Mori, Wasuke

AU - Nonoyama, Matsuo

AU - Hirotsu, Masakazu

AU - Kojima, Masaaki

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The reaction of Ni2+ with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) afforded the O-H⋯O bridged dinuclear [Ni2(HL)2] complex. When Ni2+ was allowed to react with H3L in the presence of triethylamine (3 : 2 : 6), the linear trinuclear [Ni3(L)2] complex formed, where the central nickel(II) ion is bridged by six phenolate oxygen atoms to the terminal nickel(II) ions.

AB - The reaction of Ni2+ with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) afforded the O-H⋯O bridged dinuclear [Ni2(HL)2] complex. When Ni2+ was allowed to react with H3L in the presence of triethylamine (3 : 2 : 6), the linear trinuclear [Ni3(L)2] complex formed, where the central nickel(II) ion is bridged by six phenolate oxygen atoms to the terminal nickel(II) ions.

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Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands

Abstract

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