Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands

Hiromi Ohta, Kenji Harada, Koji Irie, Setsuo Kashino, Takashi Kambe, Genta Sakane, Takashi Shibahara, Satoshi Takamizawa, Wasuke Mori, Matsuo Nonoyama, Masakazu Hirotsu, Masaaki Kojima

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29 Citations (Scopus)

Abstract

The reaction of Ni2+ with a tripodal hexadentate ligand (H3L = 1,1,1-tris(N-salicylideneaminomethyl)ethane) afforded the O-H⋯O bridged dinuclear [Ni2(HL)2] complex. When Ni2+ was allowed to react with H3L in the presence of triethylamine (3 : 2 : 6), the linear trinuclear [Ni3(L)2] complex formed, where the central nickel(II) ion is bridged by six phenolate oxygen atoms to the terminal nickel(II) ions.

Original languageEnglish
Pages (from-to)842-843
Number of pages2
JournalChemistry Letters
Issue number8
DOIs
Publication statusPublished - Jan 1 2001

ASJC Scopus subject areas

  • Chemistry(all)

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    Ohta, H., Harada, K., Irie, K., Kashino, S., Kambe, T., Sakane, G., Shibahara, T., Takamizawa, S., Mori, W., Nonoyama, M., Hirotsu, M., & Kojima, M. (2001). Di- and trinuclear nickel(II) complexes containing tripodal hexadentate ligands. Chemistry Letters, (8), 842-843. https://doi.org/10.1246/cl.2001.842