Abstract
Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.
| Original language | English |
|---|---|
| Pages (from-to) | 19-24 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 157 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Apr 28 1989 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces
Cite this
Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes. / Ata, Masafumi; Suzuki, Yasunobu; Kubozono, Yoshihiro; Aoyagi, Makoto; Gondo, Yasuhiko.
In: Chemical Physics Letters, Vol. 157, No. 1-2, 28.04.1989, p. 19-24.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes
AU - Ata, Masafumi
AU - Suzuki, Yasunobu
AU - Kubozono, Yoshihiro
AU - Aoyagi, Makoto
AU - Gondo, Yasuhiko
PY - 1989/4/28
Y1 - 1989/4/28
N2 - Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.
AB - Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.
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UR - http://www.scopus.com/inward/citedby.url?scp=0040211079&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(89)87200-8
DO - 10.1016/0009-2614(89)87200-8
M3 - Article
VL - 157
SP - 19
EP - 24
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-2
ER -