Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes

Masafumi Ata, Yasunobu Suzuki, Yoshihiro Kubozono, Makoto Aoyagi, Yasuhiko Gondo

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.

Original languageEnglish
Pages (from-to)19-24
Number of pages6
JournalChemical Physics Letters
Volume157
Issue number1-2
DOIs
Publication statusPublished - Apr 28 1989
Externally publishedYes

Fingerprint

Nitrobenzenes
nitrobenzenes
Deuterium
Cyclodextrins
Anions
deuterons
inclusions
anions
nuclear spin
high resolution
nitrobenzene

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes. / Ata, Masafumi; Suzuki, Yasunobu; Kubozono, Yoshihiro; Aoyagi, Makoto; Gondo, Yasuhiko.

In: Chemical Physics Letters, Vol. 157, No. 1-2, 28.04.1989, p. 19-24.

Research output: Contribution to journalArticle

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