Abstract
Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.
| Original language | English |
|---|---|
| Pages (from-to) | 19-24 |
| Number of pages | 6 |
| Journal | Chemical Physics Letters |
| Volume | 157 |
| Issue number | 1-2 |
| DOIs | |
| Publication status | Published - Apr 28 1989 |
| Externally published | Yes |
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Ata, M., Suzuki, Y., Kubozono, Y., Aoyagi, M., & Gondo, Y. (1989). Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes. Chemical Physics Letters, 157(1-2), 19-24. https://doi.org/10.1016/0009-2614(89)87200-8