Determination of the deuteron and alkyl-substituent hyperfine coupling constants in nitrobenzene radical anions by formation of cyclodextrin inclusion complexes

Masafumi Ata, Yasunobu Suzuki, Yoshihiro Kubozono, Makoto Aoyagi, Yasuhiko Gondo

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Stable β-cyclodextrin inclusion complexes with radical anions of thirteen different nitrobenzenes have been generated by chemical reduction in 50% aq especially in the central portions associated with the vanishing 14N nuclear spin component. The high resolution obtained permits the estimation of the small hyperfine coupling constants in the guest radicals due to deuterons and alkyl substituents.

Original languageEnglish
Pages (from-to)19-24
Number of pages6
JournalChemical Physics Letters
Volume157
Issue number1-2
DOIs
Publication statusPublished - Apr 28 1989
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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