Determination of Hydrogen Peroxide with Phenol and 4-Aminoantipyrine by the use of a Resin Modified with Manganese-Tetrakis(sulfophenyl)porphine

Yutaka Saito; Masaki Mifune; Suzuyo Nakashima; Junichi Odo; Yoshimasa Tanaka; Masahiko Chikuma; Hisashi Tanaka

doi:10.2116/analsci.3.171

Determination of Hydrogen Peroxide with Phenol and 4-Aminoantipyrine by the use of a Resin Modified with Manganese-Tetrakis(sulfophenyl)porphine

Yutaka Saito, Masaki Mifune, Suzuyo Nakashima, Junichi Odo, Yoshimasa Tanaka, Masahiko Chikuma, Hisashi Tanaka

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

An anion-exchange resin, Amberlite IRA 900 modified with manganese-tetrakis(sulfophenyl)porphine (MnTPPS,) was used in place of peroxidase for the determination of hydrogen peroxide by the following enzyme-reaction: 2H2O2+phenol+4-aminoantipyrine peroxidase quinoid dye(λmax=505 nm)+4H2O. The calibration curve was linear in the range from 5 ng to 50 jig of hydrogen peroxide with a relative standard deviation of 1.05% (n=10). The absorbance of the quinoid dye formed by the use of Mn-TPPS, reached approximately 80% of that obtained by the control peroxidase method. The activity of MnTPPS, did not deteriorate over repeated uses. Only slight interferences of foreign substances were found except for the case of ascorbic acid.

Original language	English
Pages (from-to)	171-174
Number of pages	4
Journal	Analytical Sciences
Volume	3
Issue number	2
DOIs	https://doi.org/10.2116/analsci.3.171
Publication status	Published - 1987

Keywords

Peroxidase mimesis
hydrogen peroxide
manganese-tetrakis(sulfopheny!)porphine resin
peroxidase-like activity

ASJC Scopus subject areas

Analytical Chemistry

Access to Document

10.2116/analsci.3.171

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Determination of Hydrogen Peroxide with Phenol and 4-Aminoantipyrine by the use of a Resin Modified with Manganese-Tetrakis(sulfophenyl)porphine. / Saito, Yutaka; Mifune, Masaki; Nakashima, Suzuyo; Odo, Junichi; Tanaka, Yoshimasa; Chikuma, Masahiko; Tanaka, Hisashi.

In: Analytical Sciences, Vol. 3, No. 2, 1987, p. 171-174.

Research output: Contribution to journal › Article › peer-review

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abstract = "An anion-exchange resin, Amberlite IRA 900 modified with manganese-tetrakis(sulfophenyl)porphine (MnTPPS,) was used in place of peroxidase for the determination of hydrogen peroxide by the following enzyme-reaction: 2H2O2+phenol+4-aminoantipyrine peroxidase quinoid dye(λmax=505 nm)+4H2O. The calibration curve was linear in the range from 5 ng to 50 jig of hydrogen peroxide with a relative standard deviation of 1.05% (n=10). The absorbance of the quinoid dye formed by the use of Mn-TPPS, reached approximately 80% of that obtained by the control peroxidase method. The activity of MnTPPS, did not deteriorate over repeated uses. Only slight interferences of foreign substances were found except for the case of ascorbic acid.",

keywords = "Peroxidase mimesis, hydrogen peroxide, manganese-tetrakis(sulfopheny!)porphine resin, peroxidase-like activity",

author = "Yutaka Saito and Masaki Mifune and Suzuyo Nakashima and Junichi Odo and Yoshimasa Tanaka and Masahiko Chikuma and Hisashi Tanaka",

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AU - Saito, Yutaka

AU - Mifune, Masaki

AU - Nakashima, Suzuyo

AU - Odo, Junichi

AU - Tanaka, Yoshimasa

AU - Chikuma, Masahiko

AU - Tanaka, Hisashi

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AB - An anion-exchange resin, Amberlite IRA 900 modified with manganese-tetrakis(sulfophenyl)porphine (MnTPPS,) was used in place of peroxidase for the determination of hydrogen peroxide by the following enzyme-reaction: 2H2O2+phenol+4-aminoantipyrine peroxidase quinoid dye(λmax=505 nm)+4H2O. The calibration curve was linear in the range from 5 ng to 50 jig of hydrogen peroxide with a relative standard deviation of 1.05% (n=10). The absorbance of the quinoid dye formed by the use of Mn-TPPS, reached approximately 80% of that obtained by the control peroxidase method. The activity of MnTPPS, did not deteriorate over repeated uses. Only slight interferences of foreign substances were found except for the case of ascorbic acid.

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