Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase

Yutaka Saito; Masaki Mifune; Suzuyo Nakashima; Junichi Odo; Yoshimasa Tanaka; Masahiko Chikuma; Hisashi Tanaka

doi:10.1016/0039-9140(87)80086-3

Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase

Yutaka Saito, Masaki Mifune, Suzuyo Nakashima, Junichi Odo, Yoshimasa Tanaka, Masahiko Chikuma, Hisashi Tanaka

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Amberlite IRA 900 anion-exchange resin modified with manganese-tetrakis(sulphophenyl)-porphine has been used as a catalyst instead of peroxidase for the determination of hydrogen peroxide by the reaction 2H₂O₂ + N,N-diethylaniline + 4-aminoantipyrine ^catalyst→ quinonoid dye (λ_max 550 nm) + 4H₂O. The apparent molar absorptivity for hydrogen peroxide was 1.1 × 10⁴ 1.mole^-1.cm^-1, coefficient of variation 0.7%. This value is approximately 84% of that obtained by the use of peroxidase as catalyst. Similar conditions to those in the enzymatic reaction were suitable for use of the modified resin as catalyst, and the results show it to be a good substitute for peroxidase in this reaction system.

Original language	English
Pages (from-to)	667-669
Number of pages	3
Journal	Talanta
Volume	34
Issue number	7
DOIs	https://doi.org/10.1016/0039-9140(87)80086-3
Publication status	Published - Jul 1987

ASJC Scopus subject areas

Analytical Chemistry

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10.1016/0039-9140(87)80086-3

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Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase. / Saito, Yutaka; Mifune, Masaki; Nakashima, Suzuyo; Odo, Junichi; Tanaka, Yoshimasa; Chikuma, Masahiko; Tanaka, Hisashi.

In: Talanta, Vol. 34, No. 7, 07.1987, p. 667-669.

Research output: Contribution to journal › Article › peer-review

Saito, Y, Mifune, M, Nakashima, S, Odo, J, Tanaka, Y, Chikuma, M & Tanaka, H 1987, 'Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase', Talanta, vol. 34, no. 7, pp. 667-669. https://doi.org/10.1016/0039-9140(87)80086-3

Saito, Yutaka ; Mifune, Masaki ; Nakashima, Suzuyo ; Odo, Junichi ; Tanaka, Yoshimasa ; Chikuma, Masahiko ; Tanaka, Hisashi. / Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase. In: Talanta. 1987 ; Vol. 34, No. 7. pp. 667-669.

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title = "Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase",

abstract = "Amberlite IRA 900 anion-exchange resin modified with manganese-tetrakis(sulphophenyl)-porphine has been used as a catalyst instead of peroxidase for the determination of hydrogen peroxide by the reaction 2H2O2 + N,N-diethylaniline + 4-aminoantipyrine catalyst→ quinonoid dye (λmax 550 nm) + 4H2O. The apparent molar absorptivity for hydrogen peroxide was 1.1 × 104 1.mole-1.cm-1, coefficient of variation 0.7%. This value is approximately 84% of that obtained by the use of peroxidase as catalyst. Similar conditions to those in the enzymatic reaction were suitable for use of the modified resin as catalyst, and the results show it to be a good substitute for peroxidase in this reaction system.",

author = "Yutaka Saito and Masaki Mifune and Suzuyo Nakashima and Junichi Odo and Yoshimasa Tanaka and Masahiko Chikuma and Hisashi Tanaka",

note = "Funding Information: Acknowledgement-This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture, Japan.",

year = "1987",

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doi = "10.1016/0039-9140(87)80086-3",

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T1 - Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase

AU - Saito, Yutaka

AU - Mifune, Masaki

AU - Nakashima, Suzuyo

AU - Odo, Junichi

AU - Tanaka, Yoshimasa

AU - Chikuma, Masahiko

AU - Tanaka, Hisashi

N1 - Funding Information: Acknowledgement-This work was supported in part by a Grant-in-Aid for Scientific Research from the Ministry of Education, Science and Culture, Japan.

PY - 1987/7

Y1 - 1987/7

N2 - Amberlite IRA 900 anion-exchange resin modified with manganese-tetrakis(sulphophenyl)-porphine has been used as a catalyst instead of peroxidase for the determination of hydrogen peroxide by the reaction 2H2O2 + N,N-diethylaniline + 4-aminoantipyrine catalyst→ quinonoid dye (λmax 550 nm) + 4H2O. The apparent molar absorptivity for hydrogen peroxide was 1.1 × 104 1.mole-1.cm-1, coefficient of variation 0.7%. This value is approximately 84% of that obtained by the use of peroxidase as catalyst. Similar conditions to those in the enzymatic reaction were suitable for use of the modified resin as catalyst, and the results show it to be a good substitute for peroxidase in this reaction system.

AB - Amberlite IRA 900 anion-exchange resin modified with manganese-tetrakis(sulphophenyl)-porphine has been used as a catalyst instead of peroxidase for the determination of hydrogen peroxide by the reaction 2H2O2 + N,N-diethylaniline + 4-aminoantipyrine catalyst→ quinonoid dye (λmax 550 nm) + 4H2O. The apparent molar absorptivity for hydrogen peroxide was 1.1 × 104 1.mole-1.cm-1, coefficient of variation 0.7%. This value is approximately 84% of that obtained by the use of peroxidase as catalyst. Similar conditions to those in the enzymatic reaction were suitable for use of the modified resin as catalyst, and the results show it to be a good substitute for peroxidase in this reaction system.

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Determination of hydrogen peroxide with N,N-diethylaniline and 4-aminoantipyrine by use of an anion-exchange resin modified with manganese-tetrakis(sulphophenyl)porphine, as a substitute for peroxidase

Abstract

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