Determination of band-filling change in the two-dimensional organic conductor, τ-(EDO-S,S-DMEDT-TTF)2(AuBr2) 1+y, (y ≤ 0.875) by the quantum oscillation of magnetoresistance

Harukazu Yoshino, Keizo Murata, Tsutomu Nakanishi, Lin Li, Eun Sang Choi, David Graf, James S. Brooks, Yoshio Nogami, George C. Papavassiliou

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

The effect of thermal treatment on the transport properties is studied for a two-dimensional organic conductor τ-(EDO-S,S-DMEDT-TTF) 2(AuBr2)1+y, (y ≤ 0.875). The temperature dependence of the electric resistivity below room temperature was found to be changed from metallic down to low temperature to semiconducting by heating up to 420 K. One of the two frequencies of Shubnikov-de Haas oscillations are found to be different between the non-heated and heated parts from a single crystal, while no evidence of structural change in X-ray photograph was observed. The present result clearly shows that nominal valence or band filling can be controlled by simple thermal treatment for the quasi-two-dimensional organic metal. The mechanism of the change in the band filling is discussed in terms of anion decomposition.

Original languageEnglish
Pages (from-to)417-424
Number of pages8
JournalJournal of the Physical Society of Japan
Volume74
Issue number1
DOIs
Publication statusPublished - Jan 2005

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conductors
oscillations
photographs
transport properties
anions
valence
decomposition
temperature dependence
electrical resistivity
heating
single crystals
room temperature
metals
x rays

Keywords

  • Band-filling control
  • Magnetoresistance
  • Organic conductor
  • Quantum oscillations
  • Quasi-two-dimensional system
  • Thermal treatment

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Determination of band-filling change in the two-dimensional organic conductor, τ-(EDO-S,S-DMEDT-TTF)2(AuBr2) 1+y, (y ≤ 0.875) by the quantum oscillation of magnetoresistance. / Yoshino, Harukazu; Murata, Keizo; Nakanishi, Tsutomu; Li, Lin; Choi, Eun Sang; Graf, David; Brooks, James S.; Nogami, Yoshio; Papavassiliou, George C.

In: Journal of the Physical Society of Japan, Vol. 74, No. 1, 01.2005, p. 417-424.

Research output: Contribution to journalArticle

Yoshino, Harukazu ; Murata, Keizo ; Nakanishi, Tsutomu ; Li, Lin ; Choi, Eun Sang ; Graf, David ; Brooks, James S. ; Nogami, Yoshio ; Papavassiliou, George C. / Determination of band-filling change in the two-dimensional organic conductor, τ-(EDO-S,S-DMEDT-TTF)2(AuBr2) 1+y, (y ≤ 0.875) by the quantum oscillation of magnetoresistance. In: Journal of the Physical Society of Japan. 2005 ; Vol. 74, No. 1. pp. 417-424.
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abstract = "The effect of thermal treatment on the transport properties is studied for a two-dimensional organic conductor τ-(EDO-S,S-DMEDT-TTF) 2(AuBr2)1+y, (y ≤ 0.875). The temperature dependence of the electric resistivity below room temperature was found to be changed from metallic down to low temperature to semiconducting by heating up to 420 K. One of the two frequencies of Shubnikov-de Haas oscillations are found to be different between the non-heated and heated parts from a single crystal, while no evidence of structural change in X-ray photograph was observed. The present result clearly shows that nominal valence or band filling can be controlled by simple thermal treatment for the quasi-two-dimensional organic metal. The mechanism of the change in the band filling is discussed in terms of anion decomposition.",
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AU - Li, Lin

AU - Choi, Eun Sang

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