Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction: The first example of the vic-dibromide-alkene functional group interconversion by organic selenide

Yutaka Takaguchi; Akira Hosokawa; Sachiko Yamada; Jiro Motoyoshiya; Hiromu Aoyama

doi:10.1039/a805261a

Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction: The first example of the vic-dibromide-alkene functional group interconversion by organic selenide

Yutaka Takaguchi, Akira Hosokawa, Sachiko Yamada, Jiro Motoyoshiya, Hiromu Aoyama

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Vicinal dibromoalkanes are debrominated to alkenes by treatment with 1,5-dichalcogenacyclooctane under neutral conditions induced by transannular interaction. The first example of dehalogenation by using an organoselenium compound is described.

Original language	English
Pages (from-to)	3147-3149
Number of pages	3
Journal	Journal of the Chemical Society - Perkin Transactions 1
Issue number	19
DOIs	https://doi.org/10.1039/a805261a
Publication status	Published - Oct 7 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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Takaguchi, Y., Hosokawa, A., Yamada, S., Motoyoshiya, J., & Aoyama, H. (1998). Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction: The first example of the vic-dibromide-alkene functional group interconversion by organic selenide. Journal of the Chemical Society - Perkin Transactions 1, (19), 3147-3149. https://doi.org/10.1039/a805261a

Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction : The first example of the vic-dibromide-alkene functional group interconversion by organic selenide. / Takaguchi, Yutaka; Hosokawa, Akira; Yamada, Sachiko; Motoyoshiya, Jiro; Aoyama, Hiromu.

In: Journal of the Chemical Society - Perkin Transactions 1, No. 19, 07.10.1998, p. 3147-3149.

Research output: Contribution to journal › Article › peer-review

Takaguchi, Y, Hosokawa, A, Yamada, S, Motoyoshiya, J & Aoyama, H 1998, 'Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction: The first example of the vic-dibromide-alkene functional group interconversion by organic selenide', Journal of the Chemical Society - Perkin Transactions 1, no. 19, pp. 3147-3149. https://doi.org/10.1039/a805261a

Takaguchi Y, Hosokawa A, Yamada S, Motoyoshiya J, Aoyama H. Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction: The first example of the vic-dibromide-alkene functional group interconversion by organic selenide. Journal of the Chemical Society - Perkin Transactions 1. 1998 Oct 7;(19):3147-3149. https://doi.org/10.1039/a805261a

Takaguchi, Yutaka ; Hosokawa, Akira ; Yamada, Sachiko ; Motoyoshiya, Jiro ; Aoyama, Hiromu. / Denomination of vic-dibromides with 1,5-dichalcogenacyclooctane induced by transannular chalcogen-chalcogen interaction : The first example of the vic-dibromide-alkene functional group interconversion by organic selenide. In: Journal of the Chemical Society - Perkin Transactions 1. 1998 ; No. 19. pp. 3147-3149.

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