Degradation kinetics of monosaccharides in subcritical water

Shabnam Haghighat Khajavi, Yukitaka Kimura, Toshinobu Oomori, Ryuichi Matsuno, Shuji Adachi

Research output: Contribution to journalArticle

98 Citations (Scopus)

Abstract

The degradation kinetics of the monosaccharides of both the aldohexose (glucose, galactose and mannose) and ketohexose (fructose and sorbose) types in subcritical water were studied using a tubular reactor in the temperature range of 180-260°C and at a constant pressure of 10 MPa. The relationship between the fraction of unreacted monosaccharide and the residence time could be expressed by the Weibull equation for all the monosaccharides at any temperature. The susceptibility to degradation was quite different among the saccharides. The activation energy and frequency factor were calculated from the Arrhenius equation and the enthalpy-entropy compensation was found to hold for the degradation of monosaccharides in subcritical water. The isokinetic temperature was similar to that for the hydrolysis of disaccharide. The conversion to 5-hydroxymethy-2-furaldehyde (HMF) and the decrease in pH of the effluent solution were measured and it was found that fructose had the highest value for both.

Original languageEnglish
Pages (from-to)309-313
Number of pages5
JournalJournal of Food Engineering
Volume68
Issue number3
DOIs
Publication statusPublished - Jun 2005
Externally publishedYes

Fingerprint

Monosaccharides
monosaccharides
kinetics
degradation
Water
Fructose
Temperature
aldohexoses
fructose
water
Sorbose
sorbose
Furaldehyde
temperature
Disaccharides
disaccharides
Entropy
Mannose
enthalpy
entropy

Keywords

  • Aldohexose
  • Degradation
  • Ketohexose
  • Monosaccharide
  • Subcritical water
  • Weibull equation

ASJC Scopus subject areas

  • Food Science

Cite this

Degradation kinetics of monosaccharides in subcritical water. / Khajavi, Shabnam Haghighat; Kimura, Yukitaka; Oomori, Toshinobu; Matsuno, Ryuichi; Adachi, Shuji.

In: Journal of Food Engineering, Vol. 68, No. 3, 06.2005, p. 309-313.

Research output: Contribution to journalArticle

Khajavi, Shabnam Haghighat ; Kimura, Yukitaka ; Oomori, Toshinobu ; Matsuno, Ryuichi ; Adachi, Shuji. / Degradation kinetics of monosaccharides in subcritical water. In: Journal of Food Engineering. 2005 ; Vol. 68, No. 3. pp. 309-313.
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