Cyclopropanation mediated by lithium iodide of electron-deficient alkenes with activated dibromomethylene compounds

Daisuke Kawai, Katsuaki Kawasumi, Tsukasa Miyahara, Tsunehisa Hirashita, Shuki Araki

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Reactions of electron-deficient alkenes with dibromomethylene compounds activated by cyanide and ester groups were promoted by LiI to afford the corresponding cyclopropanes in high yields.

Original languageEnglish
Pages (from-to)2977-2980
Number of pages4
JournalSynlett
Issue number19
DOIs
Publication statusPublished - Dec 1 2008
Externally publishedYes

Fingerprint

Cyclopropanes
Cyanides
Alkenes
Iodides
Lithium
Esters
Electrons

Keywords

  • Cyanides
  • Cyclopropanes
  • Dibromides
  • Esters
  • Stereoselective synthesis

ASJC Scopus subject areas

  • Organic Chemistry

Cite this

Cyclopropanation mediated by lithium iodide of electron-deficient alkenes with activated dibromomethylene compounds. / Kawai, Daisuke; Kawasumi, Katsuaki; Miyahara, Tsukasa; Hirashita, Tsunehisa; Araki, Shuki.

In: Synlett, No. 19, 01.12.2008, p. 2977-2980.

Research output: Contribution to journalArticle

Kawai, Daisuke ; Kawasumi, Katsuaki ; Miyahara, Tsukasa ; Hirashita, Tsunehisa ; Araki, Shuki. / Cyclopropanation mediated by lithium iodide of electron-deficient alkenes with activated dibromomethylene compounds. In: Synlett. 2008 ; No. 19. pp. 2977-2980.
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