Crystal structures of four isomeric hydrogen-bonded co-crystals of 6-methyl­quinoline with 2-chloro-4-nitro­benzoic acid, 2-chloro-5-nitro­benzoic acid, 3-chloro-2-nitro­benzoic acid and 4-chloro-2-nitro­benzoic acid

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Abstract

The structures of the four isomeric compounds of 6-methyl­quinoline with chloro- and nitro-substituted benzoic acids, C7H4ClNO4·C10H9N, namely, 2-chloro-4-nitro­benzoic acid-6-methyl­quinoline (1/1), (I), 2-chloro-5-nitro­benzoic acid-6-methyl­quinoline (1/1), (II), 3-chloro-2-nitro­benzoic acid-6-methyl­quinoline (1/1), (III), and 4-chloro-2-nitro­benzoic acid-6-methyl­quinoline (1/1), (IV), have been determined at 185-190 K. In each compound, the acid and base mol­ecules are linked by a short hydrogen bond between a carboxyl O atom and an N atom of the base. The O⋯N distances are 2.5452 (12), 2.6569 (13), 2.5640 (17) and 2.514 (2) Å, respectively, for compounds (I)-(IV). In the hydrogen-bonded acid-base units of (I), (III) and (IV), the H atoms are each disordered over two positions with O site:N site occupancies of 0.65 (3):0.35 (3), 0.59 (4):0.41 (4) and 0.48 (5):0.52 (5), respectively, for (I), (III) and (IV). The H atom in the hydrogen-bonded unit of (II) is located at the O-atom site. In all of the crystals of (I)-(IV), π-π inter­actions between the quinoline ring system and the benzene ring of the acid mol­ecule are observed. In addition, a π-π inter­action between the benzene rings of adjacent acid mol­ecules and a C - H⋯O hydrogen bond are observed in the crystal of (I), and C - H⋯O hydrogen bonds and O⋯Cl contacts occur in the crystals of (III) and (IV). These inter­molecular inter­actions connect the acid and base mol­ecules, forming a layer structure parallel to the bc plane in (I), a column along the a-axis direction in (II), a layer parallel to the ab plane in (III) and a three-dimensional network in (IV). Hirshfeld surfaces for the title compounds mapped over d norm and shape index were generated to visualize the weak inter­molecular inter­actions.

Original languageEnglish
Pages (from-to)1701-1707
Number of pages7
JournalActa Crystallographica Section E: Crystallographic Communications
Volume76
DOIs
Publication statusPublished - Nov 1 2020

Keywords

  • 2-chloro-4-nitro­benzoic acid
  • 2-chloro-5-nitro­benzoic acid
  • 3-chloro-2-nitro­benzoic acid
  • 4-chloro-2-nitro­benzoic acid
  • 6-methyl­quinoline
  • Hirshfeld surface
  • crystal structure
  • disorder
  • hydrogen bond

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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