Crystal structure of the low-temperature phase of α-BaCu4S3 observed by TEM and ED

Noriyuki Nagaoka, Yuji Okada, Yasuhiro Yokota, Tsukio Ohtani

Research output: Contribution to journalArticlepeer-review

Abstract

Layered ternary chalcogenide α-BaCu4S3 shows a phase transition at ca. 190K. Electron diffraction studies revealed that the transition was accompanied by the formation of a superstucture with a wave vector of q = (1/5) b*. The observed superlattice electron diffraction patterns were analyzed on the basis of a superstructure model using the multi-slice calculation method.

Original languageEnglish
Pages (from-to)465-470
Number of pages6
JournalJournal of Electron Microscopy
Volume45
Issue number6
DOIs
Publication statusPublished - Jan 1 1996

Keywords

  • Chalcogenide
  • Electron diffraction
  • Phase transition
  • Superstructure

ASJC Scopus subject areas

  • Instrumentation

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