Crystal structure and chiroptical spectra of sodium tetrakis (+)-hfbc Pr(III) complex

Dai Shirotani, Takayoshi Suzuki, Kazuaki Yamanari, Sumio Kaizaki

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The X-ray crystal structure of tetrakis (+)-hfbc Pr(III) complex, Na[Pr((+)-hfbc)4]·CH3CN, was compared with that of the corresponding Na-La complex with a pseudo-achiral dodecahedron, and the solution CD spectra were also discussed in the 4f-4f transition in consideration of the exciton CD couplet showing Δ-SAPR-8 configuration in CHCl3.

Original languageEnglish
Pages (from-to)325-328
Number of pages4
JournalJournal of Alloys and Compounds
Volume451
Issue number1-2
DOIs
Publication statusPublished - Feb 28 2008
Externally publishedYes

Keywords

  • Chiroptical spectra
  • Crystal structure
  • Pr(III)

ASJC Scopus subject areas

  • Mechanics of Materials
  • Mechanical Engineering
  • Metals and Alloys
  • Materials Chemistry

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