Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion

Yoichiro Kuninobu; Daisuke Asanoma; Kazuhiko Takai

doi:10.1055/s-0030-1259040

Cross-coupling reactions between C(sp²)-H and C(sp ³)-H bonds via sequential dehydrogenation and C-H insertion

Yoichiro Kuninobu, Daisuke Asanoma, Kazuhiko Takai

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Formal C(sp²)-H and C(sp³)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.

Original language	English
Pages (from-to)	2883-2886
Number of pages	4
Journal	Synlett
Issue number	19
DOIs	https://doi.org/10.1055/s-0030-1259040
Publication status	Published - 2010

Keywords

C-H activation
cross-coupling
dehydrogenation
iridium
manganese

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1055/s-0030-1259040

Cite this

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title = "Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion",

abstract = "Formal C(sp2)-H and C(sp3)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.",

keywords = "C-H activation, cross-coupling, dehydrogenation, iridium, manganese",

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T1 - Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion

AU - Kuninobu, Yoichiro

AU - Asanoma, Daisuke

AU - Takai, Kazuhiko

PY - 2010

Y1 - 2010

N2 - Formal C(sp2)-H and C(sp3)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.

AB - Formal C(sp2)-H and C(sp3)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.

KW - C-H activation

KW - cross-coupling

KW - dehydrogenation

KW - iridium

KW - manganese

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