Cross-coupling reactions between C(sp2)-H and C(sp 3)-H bonds via sequential dehydrogenation and C-H insertion

Yoichiro Kuninobu; Daisuke Asanoma; Kazuhiko Takai

doi:10.1055/s-0030-1259040

Cross-coupling reactions between C(sp²)-H and C(sp ³)-H bonds via sequential dehydrogenation and C-H insertion

Yoichiro Kuninobu, Daisuke Asanoma, Kazuhiko Takai

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

Formal C(sp²)-H and C(sp³)-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.

Original language	English
Pages (from-to)	2883-2886
Number of pages	4
Journal	Synlett
Issue number	19
DOIs	https://doi.org/10.1055/s-0030-1259040
Publication status	Published - Nov 19 2010

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Keywords

C-H activation
cross-coupling
dehydrogenation
iridium
manganese

ASJC Scopus subject areas

Organic Chemistry

Cite this

Kuninobu, Y., Asanoma, D., & Takai, K. (2010). Cross-coupling reactions between C(sp²)-H and C(sp ³)-H bonds via sequential dehydrogenation and C-H insertion. Synlett, (19), 2883-2886. https://doi.org/10.1055/s-0030-1259040

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10.1055/s-0030-1259040