CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.

Kazuhiko Takai; Mitsuyoshi Sato; Koichiro Oshima; Hitosi Nozaki

doi:10.1246/bcsj.57.108

CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.

Kazuhiko Takai, Mitsuyoshi Sato, Koichiro Oshima, Hitosi Nozaki

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.

Original language	English
Pages (from-to)	108-115
Number of pages	8
Journal	Bulletin of the Chemical Society of Japan
Volume	57
Issue number	1
DOIs	https://doi.org/10.1246/bcsj.57.108
Publication status	Published - Jan 1 1984
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.",

abstract = "The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.",

author = "Kazuhiko Takai and Mitsuyoshi Sato and Koichiro Oshima and Hitosi Nozaki",

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AU - Sato, Mitsuyoshi

AU - Oshima, Koichiro

AU - Nozaki, Hitosi

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AB - The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.

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CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST.

Abstract

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