Abstract
The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.
| Original language | English |
|---|---|
| Pages (from-to) | 108-115 |
| Number of pages | 8 |
| Journal | Bulletin of the Chemical Society of Japan |
| Volume | 57 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 1 1984 |
| Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
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Takai, K., Sato, M., Oshima, K., & Nozaki, H. (1984). CROSS-COUPLING REACTION BETWEEN ENOL PHOSPHATES AND ORGANOALUMINIUM COMPOUNDS IN THE PRESENCE OF PALLADIUM(0) CATALYST. Bulletin of the Chemical Society of Japan, 57(1), 108-115. https://doi.org/10.1246/bcsj.57.108