Abstract
The title reaction in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium(0) affords alkylative coupling products in good to excellent yields in 1,2-dichloroethane at room temperature. This coupling reaction under C(sp**2)-O cleavage proceeds stereospecifically. The reaction does not affect a coexisting vinyl sulfide group. This feature enables 1,2- and 1,3-carbonyl transposition with or without alkylation via phenylthio-substituted enol phosphates.
Original language | English |
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Pages (from-to) | 108-115 |
Number of pages | 8 |
Journal | Bulletin of the Chemical Society of Japan |
Volume | 57 |
Issue number | 1 |
DOIs | |
Publication status | Published - Jan 1 1984 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)