Critical Casimir effect in a polymer chain in supercritical solvents

Tomonari Sumi, Nobuyuki Imazaki, Hideo Sekino

Research output: Contribution to journalArticlepeer-review

16 Citations (Scopus)

Abstract

Density fluctuation effects on the conformation of a polymer chain in a supercritical solvent were investigated by performing a multiscale simulation based on the density-functional theory. We found (a) a universal swelling of the polymer chain near the critical point, irrespective of whether the polymer chain is solvophilic or solvophobic, and (b) a characteristic collapse of the polymer chain having a strong solvophilicity at a temperature slightly higher than the critical point, where the isothermal compressibility becomes less than the ideal one.

Original languageEnglish
Article number030801
JournalPhysical Review E - Statistical, Nonlinear, and Soft Matter Physics
Volume79
Issue number3
DOIs
Publication statusPublished - Mar 3 2009
Externally publishedYes

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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