Copper(I) salt promoted homo-coupling reaction of organosilanes

Kazutaka Ikegashira; Yasushi Nishihara; Kazunori Hirabayashi; Atsunori Mori; Tamejiro Hiyama

doi:10.1039/a701898c

Copper(I) salt promoted homo-coupling reaction of organosilanes

Kazutaka Ikegashira, Yasushi Nishihara, Kazunori Hirabayashi, Atsunori Mori, Tamejiro Hiyama

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.

Original language	English
Pages (from-to)	1039-1040
Number of pages	2
Journal	Chemical Communications
Issue number	11
DOIs	https://doi.org/10.1039/a701898c
Publication status	Published - 1997
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/a701898c

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title = "Copper(I) salt promoted homo-coupling reaction of organosilanes",

abstract = "Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.",

author = "Kazutaka Ikegashira and Yasushi Nishihara and Kazunori Hirabayashi and Atsunori Mori and Tamejiro Hiyama",

year = "1997",

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T1 - Copper(I) salt promoted homo-coupling reaction of organosilanes

AU - Ikegashira, Kazutaka

AU - Nishihara, Yasushi

AU - Hirabayashi, Kazunori

AU - Mori, Atsunori

AU - Hiyama, Tamejiro

PY - 1997

Y1 - 1997

N2 - Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.

AB - Alkenylfluorosilanes, phenylfluorosilanes or alkynylsilanes smoothly dimerize in the presence of a copper(I) salt in a polar solvent such as N,N-dimethylformamide (DMF) or dimethyl sulfoxide (DMSO) to give the 1,3-conjugated dienes, biphenyl or 1,3-conjugated diynes, respectively.

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U2 - 10.1039/a701898c

DO - 10.1039/a701898c

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JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -

Copper(I) salt promoted homo-coupling reaction of organosilanes

Abstract

ASJC Scopus subject areas

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