Copper(I) salt mediated 1,4-reduction of α,β-unsaturated ketones using hydrosilanes

Atsunori Mori, Akinori Fujita, Yasushi Nishihara, Tamejiro Hiyama

Research output: Contribution to journalArticlepeer-review

49 Citations (Scopus)

Abstract

Reduction of α,β-unsaturated ketones with HSiPhMe2 in the presence of CuF(PPh3)3·2EtOH proceeds in a 1,4-selective manner to give the corresponding saturated ketones in excellent yields.

Original languageEnglish
Pages (from-to)2159-2160
Number of pages2
JournalChemical Communications
Issue number22
DOIs
Publication statusPublished - 1997
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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