Copper-catalyzed transformation of carbonyl-ene-nitrile compounds: Vinylation, imino ene reaction, and alkynylation of 2-aza-2,4-cyclopentadienone intermediates generated via Ritter-type hydration and dehydrative cyclization reactions

Masahito Murai, Shigekazu Kawai, Koji Miki, Kouichi Ohe

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

1H-pyrrolin-2(5H)-one derivatives are easily obtained from carbonyl-ene-nitrile compounds and alkenes or alkynes by copper(II)-catalyzed tandem sequence involving vinylation or allylation as well as Ritter-type hydration and dehydrative cyclization.

Original languageEnglish
Pages (from-to)579-584
Number of pages6
JournalJournal of Organometallic Chemistry
Volume692
Issue number1-3
DOIs
Publication statusPublished - Jan 1 2007

Keywords

  • Allylation
  • Azacyclopentadienone
  • Carbonyl-ene-nitrile
  • Copper(II)-catalysis
  • Pyrrolinone
  • Vinylation

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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