Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

Michihiro Miyake; Osamu Kaji; Shin Nagahara; Takashi Suzuki

doi:10.1039/F29868200687

Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

Michihiro Miyake, Osamu Kaji, Shin Nagahara, Takashi Suzuki

Research output: Contribution to journal › Article › peer-review

Abstract

The coordination structure of Zn^II ions in HCONH₂-HCOONH₄-ZnO solution, where the molar ratio of HCOONH₄ and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that Zn^II ions from mononuclear Zn(HCOO)₂(HCONH₂)₂ tetrahedra with a Zn-O bond length of 1.99 Å in HCONH₂-HCOONH₄ solution.

Original language	English
Pages (from-to)	687-694
Number of pages	8
Journal	Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Volume	82
Issue number	4
DOIs	https://doi.org/10.1039/F29868200687
Publication status	Published - 1986
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Physical and Theoretical Chemistry

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10.1039/F29868200687

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Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation. / Miyake, Michihiro; Kaji, Osamu; Nagahara, Shin et al.

In: Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, Vol. 82, No. 4, 1986, p. 687-694.

Research output: Contribution to journal › Article › peer-review

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title = "Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation",

abstract = "The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 {\AA} in HCONH2-HCOONH4 solution.",

author = "Michihiro Miyake and Osamu Kaji and Shin Nagahara and Takashi Suzuki",

year = "1986",

doi = "10.1039/F29868200687",

language = "English",

volume = "82",

pages = "687--694",

journal = "Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics",

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publisher = "Faraday Division of the Chemical Society",

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T1 - Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

AU - Miyake, Michihiro

AU - Kaji, Osamu

AU - Nagahara, Shin

AU - Suzuki, Takashi

PY - 1986

Y1 - 1986

N2 - The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 Å in HCONH2-HCOONH4 solution.

AB - The coordination structure of ZnII ions in HCONH2-HCOONH4-ZnO solution, where the molar ratio of HCOONH4 and ZnO is ca. 2.0, has been investigated using EXAFS (extended X-ray absorption fine structure) and RDF (radial distribution function) methods. From both results we found that ZnII ions from mononuclear Zn(HCOO)2(HCONH2)2 tetrahedra with a Zn-O bond length of 1.99 Å in HCONH2-HCOONH4 solution.

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Coordination structure of zinc(II) ions in a mixed-solvent system of formamide and ammonium formate. An EXAFS and RDF investigation

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