Coordination of aluminum in new glasses of the system Al-Cd-O-F

Osaka Akiyoshi, Fu Jie, Takada Jun, Miura Yoshinari, Maekawa Hideki

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3 Citations (Scopus)

Abstract

New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by 27Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H2O)6]3+ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.

Original languageEnglish
Pages (from-to)369-372
Number of pages4
JournalMaterials Letters
Volume12
Issue number5
DOIs
Publication statusPublished - Dec 1991

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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    Akiyoshi, O., Jie, F., Jun, T., Yoshinari, M., & Hideki, M. (1991). Coordination of aluminum in new glasses of the system Al-Cd-O-F. Materials Letters, 12(5), 369-372. https://doi.org/10.1016/0167-577X(91)90118-P