Coordination of aluminum in new glasses of the system Al-Cd-O-F

Osaka Akiyoshi, Fu Jie, Takada Jun, Miura Yoshinari, Maekawa Hideki

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

New glasses were obtained in the system Al-Cd-Pb-O-F and investigated by 27Al magic angle spinning nuclear magnetic resonance spectroscopy. The chemical shift with respect to [Al(H2O)6]3+ indicated the presence of both four- and six-coordinated Al atoms (Al(4) and Al(6) units) in the glasses. Not only the fraction of Al (6) but also the number of fluorine atoms taking part in Al(6) increased with increasing fluorine content.

Original languageEnglish
Pages (from-to)369-372
Number of pages4
JournalMaterials Letters
Volume12
Issue number5
DOIs
Publication statusPublished - 1991

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Fluorine
Aluminum
fluorine
aluminum
Glass
Atoms
Magic angle spinning
glass
magnetic resonance spectroscopy
Chemical shift
metal spinning
Nuclear magnetic resonance spectroscopy
chemical equilibrium
atoms
nuclear magnetic resonance

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

Akiyoshi, O., Jie, F., Jun, T., Yoshinari, M., & Hideki, M. (1991). Coordination of aluminum in new glasses of the system Al-Cd-O-F. Materials Letters, 12(5), 369-372. https://doi.org/10.1016/0167-577X(91)90118-P

Coordination of aluminum in new glasses of the system Al-Cd-O-F. / Akiyoshi, Osaka; Jie, Fu; Jun, Takada; Yoshinari, Miura; Hideki, Maekawa.

In: Materials Letters, Vol. 12, No. 5, 1991, p. 369-372.

Research output: Contribution to journalArticle

Akiyoshi, O, Jie, F, Jun, T, Yoshinari, M & Hideki, M 1991, 'Coordination of aluminum in new glasses of the system Al-Cd-O-F', Materials Letters, vol. 12, no. 5, pp. 369-372. https://doi.org/10.1016/0167-577X(91)90118-P
Akiyoshi, Osaka ; Jie, Fu ; Jun, Takada ; Yoshinari, Miura ; Hideki, Maekawa. / Coordination of aluminum in new glasses of the system Al-Cd-O-F. In: Materials Letters. 1991 ; Vol. 12, No. 5. pp. 369-372.
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