TY - JOUR
T1 - Convergent synthesis of the EFGH ring system of ciguatoxin CTX3C
AU - Kadota, Isao
AU - Sato, Yuki
AU - Fujita, Naoya
AU - Takamura, Hiroyoshi
AU - Yamamoto, Yoshinori
N1 - Publisher Copyright:
© 2015 Elsevier Ltd.
Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 2015/8/7
Y1 - 2015/8/7
N2 - Abstract Convergent synthesis of the EFGH ring segment of ciguatoxin CTX3C was investigated by using the intramolecular allylation of an α-chloroacetoxy ether and/or O,S-acetal, and subsequent ring-closing metathesis. A new method for the preparation of γ-alkoxyallylstannane is also described.
AB - Abstract Convergent synthesis of the EFGH ring segment of ciguatoxin CTX3C was investigated by using the intramolecular allylation of an α-chloroacetoxy ether and/or O,S-acetal, and subsequent ring-closing metathesis. A new method for the preparation of γ-alkoxyallylstannane is also described.
KW - Ciguatoxin CTX3C
KW - Convergent synthesis
KW - Intramolecular allylation
KW - Marine polycyclic ether
KW - Ring-closing metathesis
UR - http://www.scopus.com/inward/record.url?scp=84938749637&partnerID=8YFLogxK
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U2 - 10.1016/j.tet.2015.04.106
DO - 10.1016/j.tet.2015.04.106
M3 - Article
AN - SCOPUS:84938749637
VL - 71
SP - 6547
EP - 6558
JO - Tetrahedron
JF - Tetrahedron
SN - 0040-4020
IS - 37
M1 - 26709
ER -