A cationic rhodium(I) catalyst turns 2-silyl-1-alkenylboronate, readily prepared from a terminal alkyne, into the corresponding allylboronate species, which immediately undergoes nucleophilic addition to an aldehyde to give a syn-homoallylic alcohol stereoselectively.
|Number of pages||4|
|Journal||Journal of the American Chemical Society|
|Publication status||Published - Apr 30 2014|
ASJC Scopus subject areas
- Colloid and Surface Chemistry