Abstract
A sequential reductive 1,2-elimination and hydride addition process for 3,4-disubstituted butenoates derived from penicillin is successfully performed with the aid of a combination of tributyltin hydride and copper(I) chloride in N-methyl-2-pyrrolidinone (NMP) to afford 3-norcephalosporin.
| Original language | English |
|---|---|
| Pages (from-to) | 2705-2706 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Issue number | 24 |
| Publication status | Published - 1996 |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Construction of cephem framework via sequential reductive 1,2-elimination-hydride addition in a tributyltin hydride-copper(I) chloride-NMP system : Synthesis of 3-norcephalosporin. / Tanaka, Hideo; Yamaguchi, Yoshihiko; Sumida, Shin Ichi; Torii, Sigeru.
In: Chemical Communications, No. 24, 1996, p. 2705-2706.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Construction of cephem framework via sequential reductive 1,2-elimination-hydride addition in a tributyltin hydride-copper(I) chloride-NMP system
T2 - Synthesis of 3-norcephalosporin
AU - Tanaka, Hideo
AU - Yamaguchi, Yoshihiko
AU - Sumida, Shin Ichi
AU - Torii, Sigeru
PY - 1996
Y1 - 1996
N2 - A sequential reductive 1,2-elimination and hydride addition process for 3,4-disubstituted butenoates derived from penicillin is successfully performed with the aid of a combination of tributyltin hydride and copper(I) chloride in N-methyl-2-pyrrolidinone (NMP) to afford 3-norcephalosporin.
AB - A sequential reductive 1,2-elimination and hydride addition process for 3,4-disubstituted butenoates derived from penicillin is successfully performed with the aid of a combination of tributyltin hydride and copper(I) chloride in N-methyl-2-pyrrolidinone (NMP) to afford 3-norcephalosporin.
UR - http://www.scopus.com/inward/record.url?scp=0030479036&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0030479036&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0030479036
SP - 2705
EP - 2706
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 24
ER -