Abstract
O1s binding energy measured by X-ray photoelectron spectroscopy (XPS) is candidate as a new tool to determine a new scale of Lewis basicity of oxide ions in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, were compared with the experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use needed some modification in parameters. A new empirical expression introduced in this paper gives a new concept and universal scale of basicity.
| Original language | English |
|---|---|
| Pages (from-to) | 44-50 |
| Number of pages | 7 |
| Journal | Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan |
| Volume | 113 |
| Issue number | 1313 |
| DOIs | |
| Publication status | Published - Jan 2005 |
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Keywords
- Basicity
- Chemical shift
- Glass
- O1s binding energy
- XPS
ASJC Scopus subject areas
- Ceramics and Composites
Cite this
Consideration on the correlation between basicity of oxide glasses and O1s chemical shift in XPS. / Nanba, Tokuro; Miura, Yoshinari; Sakida, Shinichi.
In: Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, Vol. 113, No. 1313, 01.2005, p. 44-50.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Consideration on the correlation between basicity of oxide glasses and O1s chemical shift in XPS
AU - Nanba, Tokuro
AU - Miura, Yoshinari
AU - Sakida, Shinichi
PY - 2005/1
Y1 - 2005/1
N2 - O1s binding energy measured by X-ray photoelectron spectroscopy (XPS) is candidate as a new tool to determine a new scale of Lewis basicity of oxide ions in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, were compared with the experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use needed some modification in parameters. A new empirical expression introduced in this paper gives a new concept and universal scale of basicity.
AB - O1s binding energy measured by X-ray photoelectron spectroscopy (XPS) is candidate as a new tool to determine a new scale of Lewis basicity of oxide ions in glass. Some mathematical expressions for the basicity or XPS chemical shift, such as charge parameter and optical basicity, were compared with the experimental O1s binding energy in binary alkali oxide glasses. The expressions so far in use needed some modification in parameters. A new empirical expression introduced in this paper gives a new concept and universal scale of basicity.
KW - Basicity
KW - Chemical shift
KW - Glass
KW - O1s binding energy
KW - XPS
UR - http://www.scopus.com/inward/record.url?scp=13844281416&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=13844281416&partnerID=8YFLogxK
U2 - 10.2109/jcersj.113.44
DO - 10.2109/jcersj.113.44
M3 - Article
VL - 113
SP - 44
EP - 50
JO - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
JF - Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan
SN - 1882-0743
IS - 1313
ER -