Conglomerate crystallization, chiral recognition and spin-crossover in a host-guest complex consisting of FeIII complexes (host) and [Cr(ox)3]3- (guest)

Yukinari Sunatsuki, Sho Miyahara, Yuu Sasaki, Takayoshi Suzuki, Masaaki Kojima, Naohide Matsumoto

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

A host-guest complex, [FeIII(H3L)][Fe III(L)][CrIII(ox)3]·3H2O (1), where H3L and L3- serve as hexadentate ligands, was prepared. In 1, three properties are united: the homochiral assembly of chiral [FeIII(H3L)]3+ and [FeIII(L)] into a conglomerate structure, the chiral recognition of the host FeIII assembly to the guest [CrIII(ox)3]3- and the spin-crossover of [FeIII(H3L)]3+.

Original languageEnglish
Pages (from-to)6377-6380
Number of pages4
JournalCrystEngComm
Volume14
Issue number20
DOIs
Publication statusPublished - Oct 21 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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