Concurrent Formation of Carbon-Carbon Bonds and Functionalized Graphene by Oxidative Carbon-Hydrogen Coupling Reaction

Kumika Morioku, Naoki Morimoto, Yasuo Takeuchi, Yuta Nishina

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Oxidative C-H coupling reactions were conducted using graphene oxide (GO) as an oxidant. GO showed high selectivity compared with commonly used oxidants such as (diacetoxyiodo) benzene and 2,3-dichloro-5,6-dicyano-p-benzoquinone. A mechanistic study revealed that radical species contributed to the reaction. After the oxidative coupling reaction, GO was reduced to form a material that shows electron conductivity and high specific capacitance. Therefore, this system could concurrently achieve two important reactions: C-C bond formation via C-H transformation and production of functionalized graphene.

Original languageEnglish
Article number25824
JournalScientific Reports
Volume6
DOIs
Publication statusPublished - May 16 2016

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Hydrogen
Carbon
Oxides
Oxidants
Benzene
Capacitance
Electrons

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  • General

Cite this

Concurrent Formation of Carbon-Carbon Bonds and Functionalized Graphene by Oxidative Carbon-Hydrogen Coupling Reaction. / Morioku, Kumika; Morimoto, Naoki; Takeuchi, Yasuo; Nishina, Yuta.

In: Scientific Reports, Vol. 6, 25824, 16.05.2016.

Research output: Contribution to journalArticle

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