Abstract
Oxidative C-H coupling reactions were conducted using graphene oxide (GO) as an oxidant. GO showed high selectivity compared with commonly used oxidants such as (diacetoxyiodo) benzene and 2,3-dichloro-5,6-dicyano-p-benzoquinone. A mechanistic study revealed that radical species contributed to the reaction. After the oxidative coupling reaction, GO was reduced to form a material that shows electron conductivity and high specific capacitance. Therefore, this system could concurrently achieve two important reactions: C-C bond formation via C-H transformation and production of functionalized graphene.
| Original language | English |
|---|---|
| Article number | 25824 |
| Journal | Scientific Reports |
| Volume | 6 |
| DOIs | |
| Publication status | Published - May 16 2016 |
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ASJC Scopus subject areas
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Cite this
Concurrent Formation of Carbon-Carbon Bonds and Functionalized Graphene by Oxidative Carbon-Hydrogen Coupling Reaction. / Morioku, Kumika; Morimoto, Naoki; Takeuchi, Yasuo; Nishina, Yuta.
In: Scientific Reports, Vol. 6, 25824, 16.05.2016.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Concurrent Formation of Carbon-Carbon Bonds and Functionalized Graphene by Oxidative Carbon-Hydrogen Coupling Reaction
AU - Morioku, Kumika
AU - Morimoto, Naoki
AU - Takeuchi, Yasuo
AU - Nishina, Yuta
PY - 2016/5/16
Y1 - 2016/5/16
N2 - Oxidative C-H coupling reactions were conducted using graphene oxide (GO) as an oxidant. GO showed high selectivity compared with commonly used oxidants such as (diacetoxyiodo) benzene and 2,3-dichloro-5,6-dicyano-p-benzoquinone. A mechanistic study revealed that radical species contributed to the reaction. After the oxidative coupling reaction, GO was reduced to form a material that shows electron conductivity and high specific capacitance. Therefore, this system could concurrently achieve two important reactions: C-C bond formation via C-H transformation and production of functionalized graphene.
AB - Oxidative C-H coupling reactions were conducted using graphene oxide (GO) as an oxidant. GO showed high selectivity compared with commonly used oxidants such as (diacetoxyiodo) benzene and 2,3-dichloro-5,6-dicyano-p-benzoquinone. A mechanistic study revealed that radical species contributed to the reaction. After the oxidative coupling reaction, GO was reduced to form a material that shows electron conductivity and high specific capacitance. Therefore, this system could concurrently achieve two important reactions: C-C bond formation via C-H transformation and production of functionalized graphene.
UR - http://www.scopus.com/inward/record.url?scp=84975270830&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84975270830&partnerID=8YFLogxK
U2 - 10.1038/srep25824
DO - 10.1038/srep25824
M3 - Article
AN - SCOPUS:84975270830
VL - 6
JO - Scientific Reports
JF - Scientific Reports
SN - 2045-2322
M1 - 25824
ER -