Abstract
Concise syntheses of the DE and GH ring segments of gambierol (1) were achieved by the palladium-catalyzed coupling of ketene acetal triflates and a zinc homoenolate, followed by the hydroboration of the resulting cyclic enol ethers and subsequent lactonization.
| Original language | English |
|---|---|
| Pages (from-to) | 4729-4731 |
| Number of pages | 3 |
| Journal | Tetrahedron Letters |
| Volume | 42 |
| Issue number | 28 |
| DOIs | |
| Publication status | Published - Jul 9 2001 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
Cite this
Concise synthesis of cyclic ethers via the palladium-catalyzed coupling of ketene acetal triflates and a zinc homoenolate. Synthesis of the DE and GH ring segments of gambierol. / Kadota, Isao; Takamura, Hiroyoshi; Sato, Kumi; Yamamoto, Yoshinori.
In: Tetrahedron Letters, Vol. 42, No. 28, 09.07.2001, p. 4729-4731.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Concise synthesis of cyclic ethers via the palladium-catalyzed coupling of ketene acetal triflates and a zinc homoenolate. Synthesis of the DE and GH ring segments of gambierol
AU - Kadota, Isao
AU - Takamura, Hiroyoshi
AU - Sato, Kumi
AU - Yamamoto, Yoshinori
PY - 2001/7/9
Y1 - 2001/7/9
N2 - Concise syntheses of the DE and GH ring segments of gambierol (1) were achieved by the palladium-catalyzed coupling of ketene acetal triflates and a zinc homoenolate, followed by the hydroboration of the resulting cyclic enol ethers and subsequent lactonization.
AB - Concise syntheses of the DE and GH ring segments of gambierol (1) were achieved by the palladium-catalyzed coupling of ketene acetal triflates and a zinc homoenolate, followed by the hydroboration of the resulting cyclic enol ethers and subsequent lactonization.
UR - http://www.scopus.com/inward/record.url?scp=0035833075&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0035833075&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(01)00824-3
DO - 10.1016/S0040-4039(01)00824-3
M3 - Article
VL - 42
SP - 4729
EP - 4731
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 28
ER -