Competition between electroauxiliaries. Selective electrochemical oxidation of heteroatom compounds having silicon and tin on the same carbon

Jun Ichi Yoshida, Mitsuru Watanabe, Hideaki Toshioka, Masayuki Imagawa, Seiji Suga

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The selective electrochemical oxidation of heteroatom compounds having two different types of electroauxiliaries, i.e. silicon and tin on the same α carbon has been achieved. The C-Sn bond was cleaved selectively and a nucleophile was introduced. The second oxidation of the compound thus obtained gave rise to the cleavage of the C-Si bond and the introduction of a second nucleophile. The present study indicates the feasibility of the redox potential based strategies using electroauxiliaries.

Original languageEnglish
Pages (from-to)1011-1012
Number of pages2
JournalChemistry Letters
Issue number10
Publication statusPublished - 1998
Externally publishedYes

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Tin compounds
Silicon compounds
Nucleophiles
Electrochemical oxidation
Carbon
Tin
Silicon
Oxidation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Competition between electroauxiliaries. Selective electrochemical oxidation of heteroatom compounds having silicon and tin on the same carbon. / Yoshida, Jun Ichi; Watanabe, Mitsuru; Toshioka, Hideaki; Imagawa, Masayuki; Suga, Seiji.

In: Chemistry Letters, No. 10, 1998, p. 1011-1012.

Research output: Contribution to journalArticle

Yoshida, Jun Ichi ; Watanabe, Mitsuru ; Toshioka, Hideaki ; Imagawa, Masayuki ; Suga, Seiji. / Competition between electroauxiliaries. Selective electrochemical oxidation of heteroatom compounds having silicon and tin on the same carbon. In: Chemistry Letters. 1998 ; No. 10. pp. 1011-1012.
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