Abstract
Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.
| Original language | English |
|---|---|
| Pages (from-to) | 782-783 |
| Number of pages | 2 |
| Journal | Chemistry Letters |
| Issue number | 7 |
| Publication status | Published - 2000 |
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ASJC Scopus subject areas
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Cite this
Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols. / Ema, Tadashi; Yamaguchi, Kunihiro; Wakasa, Yuji; Tanaka, Nobuaki; Utaka, Masanori; Sakai, Takashi.
In: Chemistry Letters, No. 7, 2000, p. 782-783.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols
AU - Ema, Tadashi
AU - Yamaguchi, Kunihiro
AU - Wakasa, Yuji
AU - Tanaka, Nobuaki
AU - Utaka, Masanori
AU - Sakai, Takashi
PY - 2000
Y1 - 2000
N2 - Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.
AB - Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.
UR - http://www.scopus.com/inward/record.url?scp=0034339552&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0034339552&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034339552
SP - 782
EP - 783
JO - Chemistry Letters
JF - Chemistry Letters
SN - 0366-7022
IS - 7
ER -