Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

Tadashi Ema, Kunihiro Yamaguchi, Yuji Wakasa, Nobuaki Tanaka, Masanori Utaka, Takashi Sakai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.

Original languageEnglish
Pages (from-to)782-783
Number of pages2
JournalChemistry Letters
Issue number7
DOIs
Publication statusPublished - Jan 1 2000

ASJC Scopus subject areas

  • Chemistry(all)

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