Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

Tadashi Ema; Kunihiro Yamaguchi; Yuji Wakasa; Nobuaki Tanaka; Masanori Utaka; Takashi Sakai

doi:10.1246/cl.2000.782

Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

Tadashi Ema, Kunihiro Yamaguchi, Yuji Wakasa, Nobuaki Tanaka, Masanori Utaka, Takashi Sakai

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.

Original language	English
Pages (from-to)	782-783
Number of pages	2
Journal	Chemistry Letters
Issue number	7
DOIs	https://doi.org/10.1246/cl.2000.782
Publication status	Published - Jan 1 2000

ASJC Scopus subject areas

Chemistry(all)

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title = "Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols",

abstract = "Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.",

author = "Tadashi Ema and Kunihiro Yamaguchi and Yuji Wakasa and Nobuaki Tanaka and Masanori Utaka and Takashi Sakai",

year = "2000",

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doi = "10.1246/cl.2000.782",

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journal = "Chemistry Letters",

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T1 - Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

AU - Ema, Tadashi

AU - Yamaguchi, Kunihiro

AU - Wakasa, Yuji

AU - Tanaka, Nobuaki

AU - Utaka, Masanori

AU - Sakai, Takashi

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.

AB - Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.

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DO - 10.1246/cl.2000.782

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JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 7

ER -

Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

Abstract

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