Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols

Tadashi Ema, Kunihiro Yamaguchi, Yuji Wakasa, Nobuaki Tanaka, Masanori Utaka, Takashi Sakai

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Thermodynamic parameters for subtilisin-catalyzed kinetic resolutions of secondary alcohols were determined, and a compensation effect between ΔΔH‡ and ΔΔS‡ was found. These data are explained in terms of the transition-state model.

Original languageEnglish
Pages (from-to)782-783
Number of pages2
JournalChemistry Letters
Issue number7
Publication statusPublished - 2000

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Subtilisin
Enthalpy
Entropy
Chemical activation
Alcohols
Thermodynamics
Kinetics
Compensation and Redress

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols. / Ema, Tadashi; Yamaguchi, Kunihiro; Wakasa, Yuji; Tanaka, Nobuaki; Utaka, Masanori; Sakai, Takashi.

In: Chemistry Letters, No. 7, 2000, p. 782-783.

Research output: Contribution to journalArticle

Ema, Tadashi ; Yamaguchi, Kunihiro ; Wakasa, Yuji ; Tanaka, Nobuaki ; Utaka, Masanori ; Sakai, Takashi. / Compensation effect between differential activation enthalpy and entropy in subtilisin-catalyzed kinetic resolutions of secondary alcohols. In: Chemistry Letters. 2000 ; No. 7. pp. 782-783.
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AU - Ema, Tadashi

AU - Yamaguchi, Kunihiro

AU - Wakasa, Yuji

AU - Tanaka, Nobuaki

AU - Utaka, Masanori

AU - Sakai, Takashi

PY - 2000

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