Cobalt(III) complex [CoL3] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine)

Synthesis, characterization and crystal structure

Aliakbar D. Khalaji, Sepideh Maghsodlou Rad, Gholamhossein Grivani, Morteza Rezaei, Kazuma Gotoh, Hiroyuki Ishida

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

Cobalt(III) complex [CoL3], where L=(5-bromo-2-hydroxybenzyl-2- furylmethyl)imine, has been synthesized by reacting cobalt(II) nitrate with L. The complex has been characterized by elemental analysis and FT-IR spectroscopy. The crystal structure of [CoL3] was determined by X-ray crystallography from single crystal data. It crystallizes in the triclinic space group P1̄ with unit cell parameters:a=9.6644(10) Å,b=11.5657(11) Å,c=16.5809(17) Å,α=102.833(4)°,β=102.999(3)°, γ=105.480(3)°,V=1659.9(3) Å3andZ=2. Thermal decomposition of [CoL3] was studied by thermogravimetry in order to evaluate its thermal stability and thermal decomposition pathways.

Original languageEnglish
Pages (from-to)1613-1616
Number of pages4
JournalChinese Journal of Chemistry
Volume29
Issue number8
DOIs
Publication statusPublished - Aug 2011

Fingerprint

Imines
Schiff Bases
Cobalt
Pyrolysis
Crystal structure
Ligands
X ray crystallography
Nitrates
Thermogravimetric analysis
Infrared spectroscopy
Thermodynamic stability
Single crystals
Chemical analysis

Keywords

  • Cobat(III)
  • crystal structure
  • spectroscopy
  • thermogravimetry

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Cobalt(III) complex [CoL3] derived from an asymmetric bidentate schiff base ligand L (L=(5-bromo-2-hydroxybenzyl-2-furylmethyl)-imine) : Synthesis, characterization and crystal structure. / Khalaji, Aliakbar D.; Maghsodlou Rad, Sepideh; Grivani, Gholamhossein; Rezaei, Morteza; Gotoh, Kazuma; Ishida, Hiroyuki.

In: Chinese Journal of Chemistry, Vol. 29, No. 8, 08.2011, p. 1613-1616.

Research output: Contribution to journalArticle

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AU - Khalaji, Aliakbar D.

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AU - Gotoh, Kazuma

AU - Ishida, Hiroyuki

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