Cluster size resolving analysis of CH3F-(ortho-H 2)n in solid para-hydrogen using FTIR absorption spectroscopy at 3 μm region

Yuki Miyamoto, Takamasa Momose, Hideto Kanamori

Research output: Contribution to journalArticle

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Abstract

Infrared absorption spectra of methyl fluoride with ortho-hydrogen (ortho-H2) clusters in a solid para-hydrogen (para-H2) crystal at 3.6 K were studied in the C-H stretching fundamental region (∼3000 cm-1) using an FTIR spectrometer. As shown previously, the ν3 C-F stretching fundamental band of CH3F-(ortho- H2)n (n 0, 1, 2, ⋯) clusters at 1040 cm -1 shows a series of n discrete absorption lines, which correspond to different-sized clusters. We observed three unresolved broad peaks in the C-H stretching region and applied this cluster model to them assuming the same intensity distribution function as the ν3 band. A fitting analysis successfully gave us the linewidth and lineshift of the components in each vibrational band. It was found that the separately determined linewidth, matrix shift of the band origin, and cluster shift are dependent on the vibrational mode. From the transition intensities of the monomer component derived from the fitting analysis, we discuss the mixing ratio of the vibrational modes due to Fermi resonance.

Original languageEnglish
Article number194315
JournalThe Journal of Chemical Physics
Volume137
Issue number19
DOIs
Publication statusPublished - Nov 21 2012

Fingerprint

para hydrogen
Absorption spectroscopy
Stretching
Hydrogen
absorption spectroscopy
Linewidth
Infrared absorption
vibration mode
Distribution functions
ortho hydrogen
Spectrometers
Absorption spectra
Monomers
shift
mixing ratios
Crystals
infrared absorption
fluorides
infrared spectra
monomers

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Cite this

Cluster size resolving analysis of CH3F-(ortho-H 2)n in solid para-hydrogen using FTIR absorption spectroscopy at 3 μm region. / Miyamoto, Yuki; Momose, Takamasa; Kanamori, Hideto.

In: The Journal of Chemical Physics, Vol. 137, No. 19, 194315, 21.11.2012.

Research output: Contribution to journalArticle

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AB - Infrared absorption spectra of methyl fluoride with ortho-hydrogen (ortho-H2) clusters in a solid para-hydrogen (para-H2) crystal at 3.6 K were studied in the C-H stretching fundamental region (∼3000 cm-1) using an FTIR spectrometer. As shown previously, the ν3 C-F stretching fundamental band of CH3F-(ortho- H2)n (n 0, 1, 2, ⋯) clusters at 1040 cm -1 shows a series of n discrete absorption lines, which correspond to different-sized clusters. We observed three unresolved broad peaks in the C-H stretching region and applied this cluster model to them assuming the same intensity distribution function as the ν3 band. A fitting analysis successfully gave us the linewidth and lineshift of the components in each vibrational band. It was found that the separately determined linewidth, matrix shift of the band origin, and cluster shift are dependent on the vibrational mode. From the transition intensities of the monomer component derived from the fitting analysis, we discuss the mixing ratio of the vibrational modes due to Fermi resonance.

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