Clear and transparent nanocrystals for infrared-responsive carrier transfer

Masanori Sakamoto, Tokuhisa Kawawaki, Masato Kimura, Taizo Yoshinaga, Junie Jhon M. Vequizo, Hironori Matsunaga, Chandana Sampath Kumara Ranasinghe, Akira Yamakata, Hiroyuki Matsuzaki, Akihiro Furube, Toshiharu Teranishi

Research output: Contribution to journalArticlepeer-review

27 Citations (Scopus)

Abstract

Infrared-light-induced carrier transfer is a key technology for ‘invisible’ optical devices for information communication systems and energy devices. However, clear and colourless photo-induced carrier transfer has not yet been demonstrated in the field of photochemistry, to the best of our knowledge. Here, we resolve this problem by employing short-wavelength-infrared (1400–4000 nm) localized surface plasmon resonance-induced electron injection from indium tin oxide nanocrystals to transparent metal oxides. The time-resolved infrared measurements visualize the dynamics of the carrier in this invisible system. Selective excitation of localized surface plasmon resonances causes hot electron injection with high efficiency (33%) and long-lived charge separation (~ 2–200 μs). We anticipate our study not only provides a breakthrough for plasmonic carrier transfer systems but may also stimulate the invention of state-of-the-art invisible optical devices.

Original languageEnglish
Article number406
JournalNature communications
Volume10
Issue number1
DOIs
Publication statusPublished - Dec 1 2019
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)
  • General
  • Physics and Astronomy(all)

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