Cis to trans photoisomerization of [CoCl2(CH3)2PCH2CH2CH2P(CH3)2}2, [CoCl(H20){(CH3)2PCH2CH2P(CH3)2}2]2+ and related complexes

Kazuma Oguni, Tomoji Ohishi, Masakazu Kita, Kazuo Kashiwabara, Junnosuke Fujita

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Synopsis. Ligand field irradiation of cz-[CoCl2{(CH3)2-PCH2CH2CH2P(CH3)3}2]+ in methanol and cis-[CoCl(H20)-{(CH3)2PCH2CH2P(CH3)2}2]2+ in acetonitrile at 5°C led to isomerization to the trans isomer with quantum yields of 0.010 and 0.070, respectively. The same cis to trans photoisomerization of [CoCl2(R2PCH2CH2PR2)2]+ (R=CH3, C4H9) occurred with much smaller quantum yields (ca.1X10-4) and c-[CoCl2{(C6H5)2PCHCHP(C6H5)2}2]+ was reduced to cobalt(H) species on irradiation.

Original languageEnglish
Pages (from-to)588-590
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume62
Issue number2
DOIs
Publication statusPublished - Feb 1989
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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