Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki, Atsushi Hasegawa, Hiroshi Yamaguchi, Kazuo Kashiwabara, Hideo D. Takagi

Research output: Contribution to journalArticle

Abstract

In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

Original languageEnglish
Pages (from-to)m461-m463
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume62
Issue number10
DOIs
Publication statusPublished - Oct 1 2006
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Fingerprint Dive into the research topics of 'Cis-Bis[(3-aminopropyl)dimethylphosphine-κ<sup>2</sup>N,P] palladium(II) dichloride methanol solvate'. Together they form a unique fingerprint.

  • Cite this