Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate

Takayoshi Suzuki, Atsushi Hasegawa, Hiroshi Yamaguchi, Kazuo Kashiwabara, Hideo D. Takagi

Research output: Contribution to journalArticle

Abstract

In the title compound, CM-[Pd(C5Hi14NP) 2]Cl2·CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P 2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 Å, indicating no obvious interaction.

Original languageEnglish
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume62
Issue number10
DOIs
Publication statusPublished - Oct 2006
Externally publishedYes

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dichlorides
Palladium
Chelation
seats
Anions
Methanol
Conformations
Cations
palladium
methyl alcohol
Ligands
Geometry
chelates
anions
cations
ligands
rings
geometry
configurations
interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Cis-Bis[(3-aminopropyl)dimethylphosphine-κ2N,P] palladium(II) dichloride methanol solvate. / Suzuki, Takayoshi; Hasegawa, Atsushi; Yamaguchi, Hiroshi; Kashiwabara, Kazuo; Takagi, Hideo D.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 62, No. 10, 10.2006.

Research output: Contribution to journalArticle

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AU - Takagi, Hideo D.

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