Chiroptical control in helical receptor-anion complexes

Hiromitsu Maeda, Tomohiro Shirai, Yuya Bando, Kazuto Takaishi, Masanobu Uchiyama, Atsuya Muranaka, Tsuyoshi Kawai, Masanobu Naito

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

Dimers of appropriately arranged anion-responsive π-conjugated moieties form helical structures by interaction with chiral anions. Terphenyl-bridged dimers of dipyrrolyldiketone boron complexes show chirality induced by binding l-amino acid anions, as observed by circular dichroism (CD) and circularly polarized luminescence (CPL). The preferred configurations of helical structures depend on the geometries of the terphenyl spacer moieties.

Original languageEnglish
Pages (from-to)6006-6009
Number of pages4
JournalOrganic Letters
Volume15
Issue number23
DOIs
Publication statusPublished - Dec 6 2013
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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  • Cite this

    Maeda, H., Shirai, T., Bando, Y., Takaishi, K., Uchiyama, M., Muranaka, A., Kawai, T., & Naito, M. (2013). Chiroptical control in helical receptor-anion complexes. Organic Letters, 15(23), 6006-6009. https://doi.org/10.1021/ol402895r