Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins

Chihiro Maeda, Kanae Ogawa, Kosuke Sadanaga, Kazuto Takaishi, Tadashi Ema

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

Doubly (R)-binaphthyl-strapped porphyrins with methylene chains were synthesized. The CD spectra showed the positive Cotton effect around the Soret bands, and several porphyrins showed CPL. In addition, we found that the chiral porphyrins were applicable to kinetic resolution of epoxide with CO2.

Original languageEnglish
Pages (from-to)1064-1067
Number of pages4
JournalChemical Communications
Volume55
Issue number8
DOIs
Publication statusPublished - Jan 1 2019

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Porphyrins
Epoxy Compounds
Cotton
Kinetics

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Chiroptical and catalytic properties of doubly binaphthyl-strapped chiral porphyrins. / Maeda, Chihiro; Ogawa, Kanae; Sadanaga, Kosuke; Takaishi, Kazuto; Ema, Tadashi.

In: Chemical Communications, Vol. 55, No. 8, 01.01.2019, p. 1064-1067.

Research output: Contribution to journalArticle

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