Abstract
The combination of CH2I2-ZN-Ti(OiPr)4 or CH2I2-ZN-Me3Al is effective for the selective methylenation of aldehydes. Seletive methylenation of a ketone group is performed by pretreatment of a substrate with Ti(NET2)4.
| Original language | English |
|---|---|
| Pages (from-to) | 5581-5584 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 26 |
| Issue number | 45 |
| DOIs | |
| Publication status | Published - 1985 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry
- Organic Chemistry
- Drug Discovery
Cite this
Chemoselective methylenation with a methylenedianion synthon. / Okazoe, Takashi; Hibino, Jun ichi; Takai, Kazuhiko; Nozakil, Hitosi.
In: Tetrahedron Letters, Vol. 26, No. 45, 1985, p. 5581-5584.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Chemoselective methylenation with a methylenedianion synthon
AU - Okazoe, Takashi
AU - Hibino, Jun ichi
AU - Takai, Kazuhiko
AU - Nozakil, Hitosi
PY - 1985
Y1 - 1985
N2 - The combination of CH2I2-ZN-Ti(OiPr)4 or CH2I2-ZN-Me3Al is effective for the selective methylenation of aldehydes. Seletive methylenation of a ketone group is performed by pretreatment of a substrate with Ti(NET2)4.
AB - The combination of CH2I2-ZN-Ti(OiPr)4 or CH2I2-ZN-Me3Al is effective for the selective methylenation of aldehydes. Seletive methylenation of a ketone group is performed by pretreatment of a substrate with Ti(NET2)4.
UR - http://www.scopus.com/inward/record.url?scp=0000696819&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000696819&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(01)80893-5
DO - 10.1016/S0040-4039(01)80893-5
M3 - Article
VL - 26
SP - 5581
EP - 5584
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 45
ER -