Abstract
The combination of CH2I2-ZN-Ti(OiPr)4 or CH2I2-ZN-Me3Al is effective for the selective methylenation of aldehydes. Seletive methylenation of a ketone group is performed by pretreatment of a substrate with Ti(NET2)4.
| Original language | English |
|---|---|
| Pages (from-to) | 5581-5584 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 26 |
| Issue number | 45 |
| DOIs | |
| Publication status | Published - 1985 |
| Externally published | Yes |
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Okazoe, T., Hibino, J. I., Takai, K., & Nozakil, H. (1985). Chemoselective methylenation with a methylenedianion synthon. Tetrahedron Letters, 26(45), 5581-5584. https://doi.org/10.1016/S0040-4039(01)80893-5