Charge ordered insulating state in DODHT salts

H. Nishikawa, Y. Sato, T. Kodama, K. Kikuchi, I. Ikemoto, J. Yamada, H. Oshio, Ryusuke Kondo, S. Kagoshima

Research output: Contribution to journal › Article

1 Citation (Scopus)

Abstract

Radical salts based on DODHT [(1,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene] are semiconductors at ambient pressure, but some salts (PF 6, AsF 6, and BF 4 · H 2O salts) exhibit supuerconducting transition under hydrostatic pressure. X-ray diffraction and magnetic susceptibility measurements at ambient pressure for PF 6 salt revealed that the insulating phase at ambient pressure corresponds to a charge ordering (CO) state with stripe-type charge pattern. While the similar magnetic behavior was observed for BF 4 · H 2O salt, temperature dependence of magnetic susceptibility of AsF 6 salt is quite different from those of the other salts.

Original languageEnglish
Pages (from-to)643-647
Number of pages5
JournalJournal of Low Temperature Physics
Volume142
Issue number3-4
DOIs
Publication statusPublished - Feb 2006
Externally publishedYes

Fingerprint

Salts
salts
Magnetic susceptibility
magnetic permeability
Hydrostatic pressure
1,4-dioxane
hydrostatic pressure
Semiconductor materials
X ray diffraction
temperature dependence
diffraction
x rays
Temperature

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Nishikawa, H., Sato, Y., Kodama, T., Kikuchi, K., Ikemoto, I., Yamada, J., ... Kagoshima, S. (2006). Charge ordered insulating state in DODHT salts. Journal of Low Temperature Physics, 142(3-4), 643-647. https://doi.org/10.1007/s10909-006-9106-y

Charge ordered insulating state in DODHT salts. / Nishikawa, H.; Sato, Y.; Kodama, T.; Kikuchi, K.; Ikemoto, I.; Yamada, J.; Oshio, H.; Kondo, Ryusuke; Kagoshima, S.

In: Journal of Low Temperature Physics, Vol. 142, No. 3-4, 02.2006, p. 643-647.

Research output: Contribution to journal › Article

Nishikawa, H, Sato, Y, Kodama, T, Kikuchi, K, Ikemoto, I, Yamada, J, Oshio, H, Kondo, R & Kagoshima, S 2006, 'Charge ordered insulating state in DODHT salts', Journal of Low Temperature Physics, vol. 142, no. 3-4, pp. 643-647. https://doi.org/10.1007/s10909-006-9106-y
Nishikawa H, Sato Y, Kodama T, Kikuchi K, Ikemoto I, Yamada J et al. Charge ordered insulating state in DODHT salts. Journal of Low Temperature Physics. 2006 Feb;142(3-4):643-647. https://doi.org/10.1007/s10909-006-9106-y
Nishikawa, H. ; Sato, Y. ; Kodama, T. ; Kikuchi, K. ; Ikemoto, I. ; Yamada, J. ; Oshio, H. ; Kondo, Ryusuke ; Kagoshima, S. / Charge ordered insulating state in DODHT salts. In: Journal of Low Temperature Physics. 2006 ; Vol. 142, No. 3-4. pp. 643-647.
@article{f011181782aa4e519c03e7ef6a0b2ea7,
title = "Charge ordered insulating state in DODHT salts",
abstract = "Radical salts based on DODHT [(1,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene] are semiconductors at ambient pressure, but some salts (PF 6, AsF 6, and BF 4 · H 2O salts) exhibit supuerconducting transition under hydrostatic pressure. X-ray diffraction and magnetic susceptibility measurements at ambient pressure for PF 6 salt revealed that the insulating phase at ambient pressure corresponds to a charge ordering (CO) state with stripe-type charge pattern. While the similar magnetic behavior was observed for BF 4 · H 2O salt, temperature dependence of magnetic susceptibility of AsF 6 salt is quite different from those of the other salts.",
author = "H. Nishikawa and Y. Sato and T. Kodama and K. Kikuchi and I. Ikemoto and J. Yamada and H. Oshio and Ryusuke Kondo and S. Kagoshima",
year = "2006",
month = "2",
doi = "10.1007/s10909-006-9106-y",
language = "English",
volume = "142",
pages = "643--647",
journal = "Journal of Low Temperature Physics",
issn = "0022-2291",
publisher = "Springer New York",
number = "3-4",

}

TY - JOUR

T1 - Charge ordered insulating state in DODHT salts

AU - Nishikawa, H.

AU - Sato, Y.

AU - Kodama, T.

AU - Kikuchi, K.

AU - Ikemoto, I.

AU - Yamada, J.

AU - Oshio, H.

AU - Kondo, Ryusuke

AU - Kagoshima, S.

PY - 2006/2

Y1 - 2006/2

N2 - Radical salts based on DODHT [(1,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene] are semiconductors at ambient pressure, but some salts (PF 6, AsF 6, and BF 4 · H 2O salts) exhibit supuerconducting transition under hydrostatic pressure. X-ray diffraction and magnetic susceptibility measurements at ambient pressure for PF 6 salt revealed that the insulating phase at ambient pressure corresponds to a charge ordering (CO) state with stripe-type charge pattern. While the similar magnetic behavior was observed for BF 4 · H 2O salt, temperature dependence of magnetic susceptibility of AsF 6 salt is quite different from those of the other salts.

AB - Radical salts based on DODHT [(1,4-dioxane-2,3-diyldithio)dihydrotetrathiafulvalene] are semiconductors at ambient pressure, but some salts (PF 6, AsF 6, and BF 4 · H 2O salts) exhibit supuerconducting transition under hydrostatic pressure. X-ray diffraction and magnetic susceptibility measurements at ambient pressure for PF 6 salt revealed that the insulating phase at ambient pressure corresponds to a charge ordering (CO) state with stripe-type charge pattern. While the similar magnetic behavior was observed for BF 4 · H 2O salt, temperature dependence of magnetic susceptibility of AsF 6 salt is quite different from those of the other salts.

UR - http://www.scopus.com/inward/record.url?scp=34447621549&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34447621549&partnerID=8YFLogxK

U2 - 10.1007/s10909-006-9106-y

DO - 10.1007/s10909-006-9106-y

M3 - Article

VL - 142

SP - 643

EP - 647

JO - Journal of Low Temperature Physics

JF - Journal of Low Temperature Physics

SN - 0022-2291

IS - 3-4

ER -

Access to Document