Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)

Masakazu Kita, Matsuo Nonoyama

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

2-Thienylamine (Hata) and 2-furfurylamine (Hafa) reacted with bis(acetylacetonato)palladium(II) [Pd(acac)2] in dichloromethane at room temperature to give Pd(acac)2(Hata) and Pd(acac)2(Hafa), respectively. In refluxing toluene the former amine gave [Pd(acac)(ata)]2, while with the latter no further reaction took place. In Pd(acac)2(Hata) and Pd(acac)2(Hafa) the amines were coordinated through the amino group, with one acac ligand as an OO chelate and the other γ-carbon bonded. X-ray analysis revealed that [Pd(acac)(ata)]2 was a dimer where the palladium atoms were bridged by deprotonated amino groups and coordinated with OO chelating acac ligands.

Original languageEnglish
Pages (from-to)1027-1030
Number of pages4
JournalPolyhedron
Volume12
Issue number9
DOIs
Publication statusPublished - May 1993
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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