Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)

Masakazu Kita; Matsuo Nonoyama

doi:10.1016/S0277-5387(00)87179-X

Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)

Masakazu Kita, Matsuo Nonoyama

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

2-Thienylamine (Hata) and 2-furfurylamine (Hafa) reacted with bis(acetylacetonato)palladium(II) [Pd(acac)₂] in dichloromethane at room temperature to give Pd(acac)₂(Hata) and Pd(acac)₂(Hafa), respectively. In refluxing toluene the former amine gave [Pd(acac)(ata)]₂, while with the latter no further reaction took place. In Pd(acac)₂(Hata) and Pd(acac)₂(Hafa) the amines were coordinated through the amino group, with one acac ligand as an OO chelate and the other γ-carbon bonded. X-ray analysis revealed that [Pd(acac)(ata)]₂ was a dimer where the palladium atoms were bridged by deprotonated amino groups and coordinated with OO chelating acac ligands.

Original language	English
Pages (from-to)	1027-1030
Number of pages	4
Journal	Polyhedron
Volume	12
Issue number	9
DOIs	https://doi.org/10.1016/S0277-5387(00)87179-X
Publication status	Published - May 1993
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{1013a7a9d42948a1be32f7a7e702dac9,

title = "Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)",

abstract = "2-Thienylamine (Hata) and 2-furfurylamine (Hafa) reacted with bis(acetylacetonato)palladium(II) [Pd(acac)2] in dichloromethane at room temperature to give Pd(acac)2(Hata) and Pd(acac)2(Hafa), respectively. In refluxing toluene the former amine gave [Pd(acac)(ata)]2, while with the latter no further reaction took place. In Pd(acac)2(Hata) and Pd(acac)2(Hafa) the amines were coordinated through the amino group, with one acac ligand as an OO chelate and the other γ-carbon bonded. X-ray analysis revealed that [Pd(acac)(ata)]2 was a dimer where the palladium atoms were bridged by deprotonated amino groups and coordinated with OO chelating acac ligands.",

author = "Masakazu Kita and Matsuo Nonoyama",

year = "1993",

month = may,

doi = "10.1016/S0277-5387(00)87179-X",

language = "English",

volume = "12",

pages = "1027--1030",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "9",

}

TY - JOUR

T1 - Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)

AU - Kita, Masakazu

AU - Nonoyama, Matsuo

PY - 1993/5

Y1 - 1993/5

N2 - 2-Thienylamine (Hata) and 2-furfurylamine (Hafa) reacted with bis(acetylacetonato)palladium(II) [Pd(acac)2] in dichloromethane at room temperature to give Pd(acac)2(Hata) and Pd(acac)2(Hafa), respectively. In refluxing toluene the former amine gave [Pd(acac)(ata)]2, while with the latter no further reaction took place. In Pd(acac)2(Hata) and Pd(acac)2(Hafa) the amines were coordinated through the amino group, with one acac ligand as an OO chelate and the other γ-carbon bonded. X-ray analysis revealed that [Pd(acac)(ata)]2 was a dimer where the palladium atoms were bridged by deprotonated amino groups and coordinated with OO chelating acac ligands.

AB - 2-Thienylamine (Hata) and 2-furfurylamine (Hafa) reacted with bis(acetylacetonato)palladium(II) [Pd(acac)2] in dichloromethane at room temperature to give Pd(acac)2(Hata) and Pd(acac)2(Hafa), respectively. In refluxing toluene the former amine gave [Pd(acac)(ata)]2, while with the latter no further reaction took place. In Pd(acac)2(Hata) and Pd(acac)2(Hafa) the amines were coordinated through the amino group, with one acac ligand as an OO chelate and the other γ-carbon bonded. X-ray analysis revealed that [Pd(acac)(ata)]2 was a dimer where the palladium atoms were bridged by deprotonated amino groups and coordinated with OO chelating acac ligands.

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U2 - 10.1016/S0277-5387(00)87179-X

DO - 10.1016/S0277-5387(00)87179-X

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EP - 1030

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 9

ER -

Characterization of reaction products of 2-thienylamine and 2-furfurylamine with bis(acetylacetonato)palladium(II)

Abstract

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