Characteristics of conjugated hydrocarbon based thin film transistor with ionic liquid gate dielectric

Yumiko Kaji, Keiko Ogawa, Ritsuko Eguchi, Hidenori Goto, Yasuyuki Sugawara, Takashi Kambe, Koki Akaike, Shin Gohda, Akihiko Fujiwara, Yoshihiro Kubozono

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Thin film transistors (TFTs) with ionic liquid gate dielectrics, [1-ethyl-3-methylimidazolium][bis(trifluoromethanesulfonyl)imide] (emim[TFSI]) and [1-butyl-3-methylimidazolium][hexafluorophosphate] (bmim[PF6]), are fabricated with thin films of one dimensional (1D) hydrocarbon, [7]phenacene. P-channel characteristics are observed for [7]phenacene TFTs with both ionic liquids by use of platinum electrode. The field-effect mobility μ for [7]phenacene TFT with bmim[PF6] was recorded to be 0.28 cm 2 V-1 s-1. The value of absolute threshold voltage, |VTH|, was less than 2.5 V, showing low-voltage operation. The accumulation of hole in the [7]phenacene TFTs with ionic liquids was confirmed from the voltage or time dependence of capacitance in metal-insulator-semiconductor structure, which shows that these TFTs operate electrochemically and the carriers are accumulated in the whole of [7]phenacene thin films.

Original languageEnglish
Pages (from-to)2076-2083
Number of pages8
JournalOrganic Electronics
Volume12
Issue number12
DOIs
Publication statusPublished - Dec 2011

Keywords

  • Aromatic hydrocarbon
  • Electric double layer
  • Electrochemical transistor
  • Ionic liquid
  • Low voltage operation
  • Organic FET

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Chemistry(all)
  • Condensed Matter Physics
  • Materials Chemistry
  • Electrical and Electronic Engineering

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